N-Heterocyclic Carbenes in Materials Chemistry.

Chem Rev

Department of Chemistry , Queen's University, 90 Bader Lane , Kingston , Ontario , Canada , K7L 3N6.

Published: April 2019

AI Article Synopsis

  • * Recently, NHCs have expanded their role into materials chemistry, enabling the modification of surfaces, polymers, and nanoparticles.
  • * This review explores the latest advancements in utilizing NHCs to create functional materials.

Article Abstract

N-Heterocyclic carbenes (NHCs) have become one of the most widely studied class of ligands in molecular chemistry and have found applications in fields as varied as catalysis, the stabilization of reactive molecular fragments, and biochemistry. More recently, NHCs have found applications in materials chemistry and have allowed for the functionalization of surfaces, polymers, nanoparticles, and discrete, well-defined clusters. In this review, we provide an in-depth look at recent advances in the use of NHCs for the development of functional materials.

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http://dx.doi.org/10.1021/acs.chemrev.8b00514DOI Listing

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