Herein, we disclose an interesting iron-catalyzed approach for the carbonylation of a tertiary carbon radical. The tertiary carbon radical generated from a 1,5-hydrogen atom transfer can be captured by CO gas smoothly. Various six-membered lactams were constructed chemo-selectively in high yields.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1039/c9cc02112d | DOI Listing |
Publication Analysis
Top Keywords
tertiary carbon
12
carbonylation tertiary
8
carbon radical
8
carbon radicals
4
radicals synthesis
4
synthesis lactams
4
lactams disclose
4
disclose interesting
4
interesting iron-catalyzed
4
iron-catalyzed approach
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!