Cube-Related Corner Coalesced Nets.

Molecules

Department of Chemistry, Faculty of Chemistry and Chemical Engineering, Babes-Bolyai University, Arany J. Street 11, Cluj 400028, Romania.

Published: March 2019

Finite or periodic structures containing the cube motif can be synthesized and transformed into a variety of structures both at the theoretical and real, experimental level. The rhombellation topo-geometric operation may be used to transform the cube-shape into larger units and then build light (spongy) structures with larger voids. Hyper-clusters are polyhedral structures which nodes are polyhedral structures (the same or different ones). The paper presents some hypothetical spongy structures related to the cubic primitive -net, with defects induced by cutting-off some atoms and/or bonds so that only corners are shared between two cubes. A diamondoid hyper-structure containing cube-coalesced corners was proposed for an eventual synthesis. The discussed structures are described in topological terms, particularly by sequential vertex connectivity and ring environment.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC6480543PMC
http://dx.doi.org/10.3390/molecules24071221DOI Listing

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