Introduction: The aim of this study was to evaluate the influence of final irrigation protocols and endodontic sealer on bond strength of root filling material on root dentin previously treated with photodynamic therapy (PDT).
Methods: One hundred root canals were prepared up to #F3 file of Pro-Taper system to receive the root filling material. All samples were submitted to PDT and randomly divided into five groups (n = 20) according to final irrigation protocols: Group 1-distilled water + ultrasonic activation (US); Group 2-17% EDTA; Group 3-QMix; Group 4-17% EDTA + US; Group 5-QMix + US. Each group was randomly divided into two subgroups (n = 10), according to the endodontic sealer used for cementation of gutta-percha points: AH Plus or MTA Fillapex. The bond strength was evaluated by a push-out test. The patterns of failure were observed under optical microscopy. The bond strength was evaluated using a two-way Anova followed by the Tukey post-hoc test, and the failure mode was evaluated using the chi-square test (α = 5%).
Results: The use of 17% EDTA and QMix associated or not to US improved the bond strength of root filling material with either endodontic sealer (p < 0.05). AH Plus showed higher bond strength than MTA Fillapex (p < 0.05). There was a higher predominance of cohesive failure in all groups, regardless of the tested final irrigation protocols and endodontic sealer (p < 0.05).
Conclusions: The use of 17% EDTA and QMix, regardless of association with US, and the use of AH Plus improve the bond strength of the root filling material on root dentin previously treated with PDT.
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http://dx.doi.org/10.1016/j.pdpdt.2019.03.013 | DOI Listing |
JACS Au
December 2024
Freie Universität Berlin, Physics Department, Experimental Molecular Biophysics, Arnimallee 14, 14195 Berlin, Germany.
Vibrational Stark effect (VSE) spectroscopy has become one of the most important experimental approaches to determine the strength of noncovalent, electrostatic interactions in chemistry and biology and to quantify their influence on structure and reactivity. Nitriles (C≡N) have been widely used as VSE probes, but their application has been complicated by an anomalous hydrogen bond (HB) blueshift which is not encompassed within the VSE framework. We present an empirical model describing the anomalous HB blueshift in terms of H-bonding geometry, i.
View Article and Find Full Text PDFDent Mater
December 2024
Graduate Program in Dentistry, School of Dentistry, Federal University of Rio Grande do Sul, Rua Ramiro Barcelos, Porto Alegre 2492, Brazil; Department of Conservative Dentistry, School of Dentistry, Federal University of Rio Grande do Sul, Rua Ramiro Barcelos, Porto Alegre 2492, Brazil. Electronic address:
Objectives: To evaluate the self-etch bonding potential of universal adhesive systems with varying acidic compositions by analyzing the wettability properties, topographical change, and microshear bond strength (µSBS) to enamel.
Methods: Eight universal adhesives were tested: All-Bond Universal (Bisco), Ambar Universal (FGM), Gluma Bond Universal (Kulzer), OptiBond Universal (Kerr), Peak Universal Bond (Ultradent), Prime&Bond Universal (Dentsply), Singlebond Universal (3 M ESPE), and Tetric N-Bond Universal (Ivoclar). Bovine incisors were prepared and treated with each adhesive according to the manufacturer's instructions.
Food Chem
December 2024
College of Food Science, Southwest University, Chongqing 400715, China; Chongqing Key Laboratory of Speciality Food Co-Built by Sichuan and Chongqing, Chongqing 400715, China; Key Laboratory of Luminescence Analysis and Molecular Sensing (Southwest University), Ministry of Education, Chongqing 400715, China. Electronic address:
The traditional gelatin extraction methods (acid-base) may hinder to their green applications due to mass energy consumption and pollution. Herein, we constructed a clean and sustainable gelatin extraction method, investigated the molecular mechanism of microwave treatment (0-360 min) and freeze-thaw on the gelatin extraction from the perspective of the crosslinking degree and hydrogen bonds. Microwave (0-60 min) can improve the hydrolysis degree (DH) and expose more enzyme cleavage sites of collagen by destroying the intramolecular and intermolecular covalent crosslinking.
View Article and Find Full Text PDFJ Colloid Interface Sci
December 2024
School of Materials Science and Engineering, Tianjin Key Laboratory of Materials Laminating Fabrication and Interface Control Technology, Hebei University of Technology, Tianjin 300130, China. Electronic address:
Ammonia borane (NHBH, AB) is considered a promising chemical hydrogen storage material. The development of efficient, stable, and economical catalysts for AB hydrolysis is essential for realizing the hydrogen energy economy. In this study, a series of p-p heterojunction catalysts, labeled M (P/S/Cl)-CuCoO, were fabricated using the high-temperature vapor phase method to achieve anionic interface gradient doping.
View Article and Find Full Text PDFBMC Oral Health
December 2024
Faculty of Dentistry, Innovative Dental Materials and Interfaces Research Unit (URB2i), UR 4462, Paris Cité University, 1 rue Maurice Arnoux, Montrouge, 92120, France.
Objective: To evaluate the shear bond strength (SBS) and adhesive remnant index (ARI) scores of metal brackets to glazed lithium disilicate reinforced glass-ceramics and zirconia according to various surface treatment protocols.
Methods: A total of 240 lithium disilicate ceramic (LD) and 240 zirconia (Zr) blocks were randomly divided according to sandblasting, hydrofluoric acid (HF) etching, universal primer use, and the adhesive system applied. A maxillary canine metal bracket was bonded to each sample with resin cement (Transbond XT, TXT).
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