The application of pesticides in agriculture is a widely-used way to alleviate pest stresses. However, it also introduces various environmental concerns due to the offsite movement of pesticide residues towards receiving water bodies. While the application of process-based modeling approaches can provide quantitative information on pesticide exposure, there are nonetheless growing requirements for model development and improvement to better represent various hydrological and physico-chemical conditions at watershed scale, and for better model integration to address environmental, ecological and economic concerns. The Soil and Water Assessment Tool (SWAT) is an ecohydrological model used in over 3000 published studies, including about 50 for simulating pesticide fate and transport at the watershed scale. To better understand its strengths and limitations, we conducted a rigorous review of published studies that have used SWAT for pesticide modeling. This review provides recommendations for improving the interior algorithms (fate simulation, pathway representation, transport/pollution control, and other hydrological related improvement) to better represent natural conditions, and for further extension of pesticide exposure modeling using SWAT by linking it with other models or management tools to effectively address the various concerns of environmental researchers and local decision makers. Going beyond past studies, we also recommend future improvement to fill research gaps in developing modularized field level simulation, improved BMPs, new in-pond and in-stream modules, and the incorporation of soft data. Our review pointed out a new insight of pesticide fate and transport modeling at watershed level, which should be seen as steps leading to the direction for model development, as well as better addressing management concerns of local stakeholders for model implementation.
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http://dx.doi.org/10.1016/j.scitotenv.2019.03.141 | DOI Listing |
Chemosphere
December 2024
Bursa Technical University, Department of Environmental Engineering, Bursa, Türkiye. Electronic address:
The pollution potential of a municipal wastewater treatment plant (WWTP) in Bursa, Türkiye, in terms of organochlorine pesticides (ΣOCPs), polychlorinated biphenyls (ΣPCBs), and polybrominated diphenyl ethers (ΣPBDEs), was investigated in air samples. Concentrations were determined using polyurethane foam disk samplers at key processes, such as the aeration tank (AT) and settling chamber (SC) of the WWTP and the background area (BA) at an urban site. Atmospheric concentration levels of PBDEs at the SC are 1.
View Article and Find Full Text PDFChemosphere
December 2024
Department of Civil, Urban, Earth, and Environmental Engineering, Ulsan National Institute of Science and Technology (UNIST), Ulsan, 44919, Republic of Korea. Electronic address:
Pine needle, pine bark, and soil samples were collected from various regions in South Korea, considering the suitability of vegetation samples as passive samplers. A total of 27 organochlorine pesticides (OCPs) were analyzed using gas chromatography/high-resolution mass spectrometry (GC/HRMS). The total concentrations of OCPs ranged between 650 and 3,652 pg/g dw in soil, 215 and 1384 pg/g ww in pine needles, and 456 and 1,723 pg/g ww in pine bark.
View Article and Find Full Text PDFJ Hazard Mater
December 2024
Civil & Environmental Engineering, University of Nebraska Lincoln, Lincoln, NE 68588, USA.
Little is known about the potential impact of point source contamination from seed treatment pesticide residues and degradation products in waste products in treated seed. The presence of these pesticides and their degradation products in the environment has been associated with toxic effects on non-target organisms including bees, aquatic organisms and humans. In this study, we investigated the occurrence of twenty-two pesticide residues and their degradation products in two streams receiving runoff from land-applied wet cake, applied and spilled wastewater originating at a biofuels production facility using pesticide-treated seed as a feedstock.
View Article and Find Full Text PDFJ Environ Qual
December 2024
Energy and Environmental Sustainability Laboratories, Institute for Energy and the Environment, The Pennsylvania State University, University Park, Pennsylvania, USA.
Concerns regarding per- and polyfluoroalkyl substances (PFAS) and their precursors have driven increased research into their sources, impacts, and mitigation strategies, aiming to reduce their prevalence in the environment. While much of this research has centered on known large sources of PFAS (e.g.
View Article and Find Full Text PDFJ Hazard Mater
December 2024
Beijing Advanced Innovation Center for Food Nutrition and Human Health, Department of Applied Chemistry, China Agricultural University, Beijing 100193, PR China. Electronic address:
Ipconazole (IPC) is a chiral triazole fungicide and commonly used for disease control in seeds. This study investigated the bioactivity and potential mechanism of ipconazole against pathogenic microorganisms at the chiral perspective. It explored the accumulation behavior of ipconazole enantiomers within the soil-earthworm system and evaluated its toxic effects on earthworms.
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