Having identified a set of conditions that predispose a solid-state ionic compound to a pressure-induced valence transition, we investigated a series of Bi(iii) perovskite oxides. We found such a transition below 10 GPa in every case, including one that we synthesised for the first time (double perovskite-type Ba2BiOsO6).
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| http://dx.doi.org/10.1039/c8cc09608b | DOI Listing |
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