We report herein an alkenylation of benzylic C(sp3)-H bonds with diazo compounds via carbon cation intermediates with DDQ as the oxidant in the presence of a catalytic amount of Fe(ii). Diphenylmethane, toluene, benzyl methyl sulfide and their derivatives could be applied as substrates to afford the tetra-substituted olefin products, which may serve as useful building blocks in organic synthesis.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1039/c9cc01060b | DOI Listing |
Publication Analysis
Top Keywords
alkenylation benzylic
8
bonds diazo
8
diazo compounds
8
feii-catalyzed alkenylation
4
benzylic c-h
4
c-h bonds
4
compounds report
4
report alkenylation
4
benzylic csp3-h
4
csp3-h bonds
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!