AI Article Synopsis
- A single-component ruthenium catalyst was used for chemoselective C-H arylations via micellar catalysis, allowing for the efficient creation of C-H-arylated ferrocenes.
- The method showed great flexibility with various functional groups and benefited from weak chelation assistance.
- Sustainability was highlighted through impressive atom-economy and successful recycling studies, with computational analyses supporting the ease of C-H activation aided by thioketones.
Article Abstract
Chemoselective C-H arylations were accomplished through micellar catalysis by a versatile single-component ruthenium catalyst. The strategy provided expedient access to C-H-arylated ferrocenes with wide functional-group tolerance and ample scope through weak chelation assistance. The sustainability of the C-H arylation was demonstrated by outstanding atom-economy and recycling studies. Detailed computational studies provided support for a facile C-H activation through thioketone assistance.
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| http://dx.doi.org/10.1002/anie.201901856 | DOI Listing |
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