We revisit the enduring problem of the 2×2×2 charge density wave (CDW) order in TiSe_{2}, utilizing photon energy-dependent angle-resolved photoemission spectroscopy to probe the full three-dimensional high- and low-temperature electronic structure. Our measurements demonstrate how a mismatch of dimensionality between the 3D conduction bands and the quasi-2D valence bands in this system leads to a hybridization that is strongly k_{z} dependent. While such a momentum-selective coupling can provide the energy gain required to form the CDW, we show how additional "passenger" states remain, which couple only weakly to the CDW and thus dominate the low-energy physics in the ordered phase of TiSe_{2}.
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http://dx.doi.org/10.1103/PhysRevLett.122.076404 | DOI Listing |
Ecotoxicol Environ Saf
January 2025
School of Eco-Environment, Hebei Key Laboratory of Close-to-Nature Restoration Technology of Wetlands, Hebei University, Baoding 071002, China. Electronic address:
Imidacloprid (IMI), as an emerging pollutant, is frequently detected in pesticide wastewater. Cobalt-based single-atom catalysts (Co-SACs) doped with sulfur atoms can serve as an efficient strategy to activate peroxymonosulfate (PMS) and degrade organic pollutants. The paper employed density functional theory and computational toxicology to deeply explore the mechanism and ecotoxicity of IMI when S atoms were introduced into Co-SACs for PMS activation.
View Article and Find Full Text PDFJ Colloid Interface Sci
January 2025
School of Materials Science and Engineering, Hefei University of Technology, Hefei 230009 China; Key Laboratory of Advanced Functional Materials and Devices of Anhui Province, Hefei University of Technology, Hefei 230009 China; China International S&T Cooperation Base for Advanced Energy and Environmental Materials & Anhui Provincial International S&T Cooperation Base for Advanced Energy Materials, Hefei University of Technology, Hefei 230009, China. Electronic address:
NbO has become a focus of research for its suitability as an anode material in sodium ion capacitors (SICs), due to its open ionic channels. The integration of NbO with reduced graphene oxide (rGO) is known to boost its electrical conductivity. However, the sluggish interfacial charge transfer kinetics and interface collapse of NbO/rGO pose challenges to its rate capability and durability.
View Article and Find Full Text PDFSci Rep
January 2025
Department of Physics, Faculty of Science, Fasa University, Fasa, 74616-86131, Iran.
In this work, we explored the role of a single electron in the energy of neutral and charged clusters of using data visualization and statistical techniques as a new insight. Initially, we studied the effects of one electron, time, and temperature on energy using multiple linear regression analysis with dummy variables, and the results demonstrated that all three predictors significantly affected the energy. Time had a positive impact (direct ratio effect) on the energy of , and and a negative impact (inverse ratio effect) on the energy of while temperature had a positive effect on the energy of all three sodium clusters.
View Article and Find Full Text PDFSci Rep
January 2025
School of Electrical Engineering, VIT University, Tamilnadu, 632014, India.
Int J Biol Macromol
January 2025
Jiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, Nanjing Forestry University, Nanjing 210037, China; International Innovation Center for Forest Chemicals and Materials, Nanjing Forestry University, Nanjing 210037, China. Electronic address:
Harnessing ionic gradients to generate electricity has inspired the development of nanofluidic membranes with charged nanochannels for osmotic energy conversion. However, achieving high-performance osmotic energy output remains elusive due to the trade-off between ion selectivity and nanochannel membrane permeability. In this study, we report a homogeneous nanofluidic membrane, composed of sulfonated nanoporous carbon (SPC) and TEMPO-oxidized cellulose nanofibers (T-CNF), engineered to overcome these limitations.
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