Normally, pendant drops adapt contact angles that are closer to 90° than their sessile analogues. This is due to the drop's weight that pulls the pendant drop and straightens its contact angles. In this paper, we show a case in which the opposite happens: sessile drops that adapt contact angles that are closer to 90° than their pendant analogues. To achieve these peculiar states, one needs to increase the effective gravity on the drops and then relax it again to 1 g. Apparently, this and other phenomena depend not only on the direction of the gravitational force but also on the drop's history. We show that the drop's contact angle (and resultant area) is affected by two types of histories: short-term history and long-term history. For example, if we gradually increase the effective gravity on the drop, decrease it back to 1 g, and then repeat this cycle again and again, we see that the first cycle is drastically different, whereas other cycles approach a plateau in their behavior. In addition to drop's history, we explain these observations in terms of volume conservation, drop contact area, and pinning effect. This study may be generalized for other body forces such as electrical and magnetic or accelerating systems.
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http://dx.doi.org/10.1021/acs.langmuir.8b03861 | DOI Listing |
Sci Rep
January 2025
Department of Pharmaceutical Chemistry, Semmelweis University, Hőgyes Endre U. 9, 1092, Budapest, Hungary.
Microtiter-plate-based systems are unified platforms of high-throughput experimentation (HTE). These polymeric devices are used worldwide on a daily basis-mainly in the pharmaceutical industry-for parallel syntheses, reaction optimization, various preclinical studies and high-throughput screening methods. Accordingly, laboratory automation today aims to handle these commercially available multiwell plates, making developments focused on their modifications a priority area of modern applied research.
View Article and Find Full Text PDFJ AAPOS
January 2025
Johns Hopkins University Wilmer Eye Institute, Baltimore, Maryland. Electronic address:
Background Recommendations regarding long-term postoperative activity are intended to prevent adverse events, but no common policy or best practice exists among ophthalmologists for pediatric patients. We surveyed ophthalmologists on their postoperative guidelines after the one-month postoperative period following childhood cataract and glaucoma surgeries. Methods A 28-question anonymous Qualtrics survey was distributed via listservs and social media.
View Article and Find Full Text PDFInt J Biol Macromol
January 2025
Research Institute of Interdisciplinary Science, School of Materials Science and Engineering, Dongguan University of Technology, Dongguan 523808, China; Guangdong Provincial Key Laboratory of Extreme Conditions, Dongguan 523803, China. Electronic address:
The application of chitosan in packaging has always been limited due to its brittle and hygroscopic nature. In this study, hydrophobic short-chain fatty acids (SCFAs) were utilized to modify chitosan to overcome this issue. For the first time, hydrophobic SCFAs, typically hexanoic acid and its homologs, were found to be able to dissolve chitosan in water as well as its hydrophilic analog.
View Article and Find Full Text PDFInt J Biol Macromol
January 2025
Key Laboratory of Automobile Materials, Ministry of Education, and College of Materials Science and Engineering, Jilin University, Changchun 130025, China. Electronic address:
A new type of filler was added to epoxy resin to prepare a composite coating with excellent corrosion and weathering resistance. The simple synthesis process and nonpolluting raw materials of this filler contribute to the development of green chemistry. Specifically, lignin was encapsulated in mesoporous silica, the synergistic effect between the two resulted in the formation of lignin/mesoporous silica composite particles (MSN-L) with excellent ultraviolet (UV) resistance.
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2025
State Key Laboratory of Polymer Materials Engineering, College of Polymer Science and Engineering, Sichuan University, Chengdu, Sichuan 610065, P.R. China.
Silicone rubber (SR) holds significant potential for everyday wearable devices due to its inherent sweat resistance and flexibility. However, its broader applicability is constrained by poor oil resistance and a suboptimal slip performance. In this study, we developed an SR with durable oil resistance and enhanced slip properties by forming a covalently bonded barrier layer on its surface through a one-step in situ fluorination reaction using F/N.
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