We theoretically investigate the nonlinear optical phenomena including optical bistability and four-wave mixing (FWM) process in a composite photonic-molecule cavity optomechanical system. The photonic-molecule cavity consisted of two whispering gallery mode (WGM) microcavities, where one WGM cavity is an optomechanical cavity with high-cavity dissipation κ and the other WGM cavity is an auxiliary ordinary optical cavity with high-quality factor (Q). Controlling the parameters of the system, such as the coupling strength J between the two cavities, the decay rate ratio δ of the two cavities, and the pump power P, the optical bistability can be controlled. Furthermore, the FWM process which presents the normal mode-splitting is also investigated in the FWM spectrum under different parameter regimes. Our study may provide a further insight of nonlinear phenomena in the composite photonic-molecule optomechanic systems.
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http://dx.doi.org/10.1186/s11671-019-2893-2 | DOI Listing |
Chem Sci
January 2025
Department of Chemical Engineering and Chemistry, Institute for Complex Molecular Systems, Eindhoven University of Technology 5600 MB Eindhoven The Netherlands
Using photoswitchable molecules to manipulate supramolecular interactions under light illumination has driven advancements in numerous fields, allowing for the strategic alteration of molecular systems. However, integrating the moiety responsible for these interactions into the photochromic scaffold can be complex and may hamper the switching efficiency. We thus explored a simple class of organic molecules, namely thiosemicarbazones, featuring both a photoisomerizable C[double bond, length as m-dash]N double bond and a thiourea moiety capable of hydrogen bonding.
View Article and Find Full Text PDFJ Am Chem Soc
January 2025
Department of Organic Chemistry, Faculty of Natural Sciences, Comenius University, Ilkovičova 6, Bratislava SK-842 15, Slovakia.
The development of new photochromic systems is motivated by the possibility of controlling the properties and functions of materials with high spatial and temporal resolution in a reversible manner. While there are several classes of photoswitches operating in solution, the design of systems efficiently operating in the solid state remains highly challenging, mainly due to limitations related to confinement effects. Triaryl-hydrazones represent a relatively new subclass of bistable hydrazone photoswitches exhibiting efficient / photochromism in solution.
View Article and Find Full Text PDFPhys Rev E
November 2024
William H. Miller III Department of Physics and Astronomy, Johns Hopkins University, Baltimore 21218, USA.
Composite materials made of polymers and liquid crystals have been widely employed in smart windows, optical filters, and bistable displays. However, it is often difficult to decipher the role of the polymer network architecture on the alignment and the texture of liquid crystals. In this study, we use a simple model system where a small amount of polymerizable liquid crystalline monomer is mixed in a liquid crystal that exhibits both a smectic phase and a cholesteric phase with a large helical pitch.
View Article and Find Full Text PDFNanophotonics
July 2024
University of Southampton, Southampton, UK.
Optically levitated multiple nanoparticles have emerged as a platform for studying complex fundamental physics such as non-equilibrium phenomena, quantum entanglement, and light-matter interaction, which could be applied for sensing weak forces and torques with high sensitivity and accuracy. An optical trapping landscape of increased complexity is needed to engineer the interaction between levitated particles beyond the single harmonic trap. However, existing platforms based on spatial light modulators for studying interactions between levitated particles suffered from low efficiency, instability at focal points, the complexity of optical systems, and the scalability for sensing applications.
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