A total of 14 phthalate esters (PAEs) were analysed by gas chromatography-mass spectrometry (GC-MS) to better understand its occurrence and distribution in seawater samples of M2 seamount in the Tropical Western Pacific Ocean (TWPO). The concentrations of ΣPAEs in the seawater ranged from 12.13 ng L to 60.69 ng L (av. 28.86 ng L), dominated by dibutyl phthalate (DBP), di(2‑ethylhexyl) phthalate (DEHP) and diisobutyl phthalate (DiBP). ΣPAEs concentrations in the southwest of the seamount were lower than those in the northeast, with the minima appearing above the seamount summit. Current-seamount interaction was reckoned to be the principal driving factors in the distribution of PAEs. DEHP posed a medium risk in seawater, suggesting that marine plastic pollution has become an urgent environmental issue that calls for more attention and actions. Microplastics leaching and atmospheric deposition might be the potential sources of PAEs.
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http://dx.doi.org/10.1016/j.marpolbul.2019.01.015 | DOI Listing |
Environ Pollut
December 2024
Anhui Provincial Key Laboratory of Molecular Enzymology and Mechanism of Major Diseases and Key Laboratory of Biomedicine in Gene Diseases and Health of Anhui Higher Education Institutes, College of Life Sciences, Anhui Normal University, Wuhu 241000, Anhui, China. Electronic address:
Phthalate esters (PAEs) are broadly utilized as plasticizers in industrial products, posing a significant threat to ecological security and human health. Lipase is a kind of green biocatalyst with the ability to degrade PAEs, but its application is limited due to its low stability and poor reusability. Herein, lipase from Candida rugosa (CRL) was immobilized into an organic ligand replacement MOFs (MAF-507) and cysteine modification and glutaraldehyde cross-linking were simultaneously performed to synthesize immobilized lipase (Cys-CRL@GA@MAF-507) using a one-pot method.
View Article and Find Full Text PDFSci Rep
December 2024
Computer Aided Drug Designing and Molecular Modeling Lab, Department of Bioinformatics, Alagappa University, Karaikudi, 630 003, Tamil Nadu, India.
Phthalic acid esters are pivotal plasticizers in various applications, including cosmetics, packaging materials, and medical devices. They have garnered significant attention from the scientific community due to their persistence in ecosystems. The multifaceted aspects of PAEs, encompassing leaching, transformation, and toxicity, underscore their prominence as primary components of anthropogenic waste.
View Article and Find Full Text PDFJ Sep Sci
December 2024
Departamento de Química, Universidade Federal de Santa Catarina, Florianopolis, Brazil.
This study introduces a green approach to sample preparation by applying natural deep eutectic solvents (NADES) to determine phthalates in carbonated soft drinks using high-performance liquid chromatography with diode array detector (HPLC-DAD). The method employs hollow fiber-microporous membrane liquid-liquid microextraction combined with a 96-well plate system, utilizing fatty-acid-based DES in the pores of the membranes. This methodology substantially reduces the use of organic solvents, and its efficiency is comparable to or better than conventional methods.
View Article and Find Full Text PDFEnviron Pollut
December 2024
State Key Laboratory of Environmental Criteria and Risk Assessment, Chinese Research Academy of Environmental Sciences, Beijing, 10012, China.
Phthalate acid esters (PAEs) and bisphenol A (BPA) are recognized as common endocrine disruptors associated with various adverse effects on human health. However, limitations in existing systematic studies, particularly in air detection, have raised concerns about potential health risks from inhalation exposure. In this study, PM samples were collected in Dongying, a petrochemical city, from October 27 to December 6, 2021.
View Article and Find Full Text PDFEcotoxicol Environ Saf
December 2024
School of Laboratory Medicine, Hubei University of Chinese Medicine, 16 Huangjia Lake West Road, Wuhan 430065, China; Hubei Shizhen Laboratory, Hubei University of Chinese Medicine, 16 Huangjia Lake West Road, Wuhan 430065, China. Electronic address:
Background: An increasing number of animal studies have indicated that exposure to phthalate esters (PAEs) may cause high blood pressure. However, population-based evidence is limited, particularly for pregnant women and young children.
Objective: To examine the correlation between prenatal exposure to phthalate ester metabolites (mPAEs) and blood pressure in preschool children.
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