Co/Co9S8 nanoparticles encapsulated in a N, S, and O ternary-doped carbon matrix were synthesized utilizing a Co-NSOMOF as a single precursor, and they exhibited excellent bifunctional electrocatalytic activity for the OER and HER. Impressively, the water splitting cell exhibited a low cell voltage of 1.56 V at 10 mA cm-2. The high performances were attributed to the synergistic effect and the protection of multi-heteroatom doped carbon shells for active Co/Co9S8 nanoparticles.
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http://dx.doi.org/10.1039/c9cc00196d | DOI Listing |
ChemSusChem
December 2024
TCG-CREST, Research Institute for Sustainable Energy (RISE), INDIA.
Hydrogen evolution reaction (HER) is a key reaction in electrochemical water splitting for hydrogen production leading to the development of potentially sustainable energy technology. Importantly, the catalysts required for HER must be earth-abundant for their large-scale deployment; silicates representing one such class. Herein, we have synthesized a series of transition mono- and bi- metal metasilicates (with SO32- group) using facile wet-chemical method followed by calcination at a higher temperature.
View Article and Find Full Text PDFRecent years have witnessed an intense effort to unravel magnetic field effects in electrocatalysis, as they can enhance the performance of common electrocatalysts. Both experimental and theoretical studies have shown that magnetic fields may affect, among others, the macroscopic spin-orbital ordering, charge transport, bubble release, and electron transfer kinetics. This paper highlights Electrochemical Impedance Spectroscopy (EIS) as a tool to analyze and separate the effects of magnetic field on both the oxygen reduction and evolution reactions at cobalt iron oxide electrodes.
View Article and Find Full Text PDFChemphyschem
December 2024
Ruhr Universität Bochum, Anorganische Chemie I, Universitätsstraße 150, NC 3/26, 44801, Bochum, GERMANY.
The commercialisation of PEM water electrolysis is still hindered by the necessity of using noble metals that are rare, expensive and therefore unsustainable. To replace the benchmark HER catalyst Pt with more abundant materials, promising non-noble catalysts need to be identified and optimal electrode preparation and electrolysis conditions need to be transferred between catalyst materials to reveal their full potential under industrially relevant conditions. This study investigates the optimal ink composition for spray-coating the cathode regarding the effects on electrode structure, performance and catalyst layer composition.
View Article and Find Full Text PDFPhys Rev Lett
December 2024
Dipartimento di Fisica, Sapienza Università di Roma, Piazzale Aldo Moro 5, 00187 Roma, Italy.
Hydrogen hydrates exhibit a rich phase diagram influenced by both pressure and temperature, with the so-called C_{2} phase emerging prominently above 2.5 GPa. In this phase, hydrogen molecules are densely packed within a cubic icelike lattice and the interaction with the surrounding water molecules profoundly affects their quantum rotational dynamics.
View Article and Find Full Text PDFPhys Chem Chem Phys
December 2024
Department of Applied Physics, Xi'an University of Technology, Xi'an 710054, China.
Two-dimensional van der Waals heterojunction materials have demonstrated significant potential for photocatalytic water splitting in hydrogen production, owing to their distinct electronic and optical properties. Among these materials, direct Z-scheme heterojunctions have attracted considerable attention in recent research. In this study, a novel CdO/ZrSSe heterojunction is designed using first-principles calculations.
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