We investigate the scaling of the interfacial adsorption of the two-dimensional Blume-Capel model using Monte Carlo simulations. In particular, we study the finite-size scaling behavior of the interfacial adsorption of the pure model at both its first- and second-order transition regimes, as well as at the vicinity of the tricritical point. Our analysis benefits from the currently existing quite accurate estimates of the relevant (tri)critical-point locations. In all studied cases, the numerical results verify to a level of high accuracy the expected scenarios derived from analytic free-energy scaling arguments. We also investigate the size dependence of the interfacial adsorption under the presence of quenched bond randomness at the originally first-order transition regime (disorder-induced continuous transition) and the relevant self-averaging properties of the system. For this ex-first-order regime, where strong transient effects are shown to be present, our findings support the scenario of a non-divergent scaling, similar to that found in the original second-order transition regime of the pure model.
Download full-text PDF |
Source |
---|---|
http://dx.doi.org/10.1103/PhysRevE.99.012111 | DOI Listing |
Soft Matter
January 2025
Biophysical Chemistry Laboratory, Centre for Interdisciplinary Research in Basic Sciences, Jamia Millia Islamia, New Delhi, India.
The adsorption and aggregation of amphiphiles at different solvent interfaces are of great scientific and technological importance. In this study, interfacial tension measurements of surface-active compounds-ionic liquid 2-dodecyl-2,2dimethylethanolammonium bromide (12Cho.Br) and cationic surfactant cetyltrimethylammonium bromide (CTAB)-were conducted both in the absence and presence of ciprofloxacin (CIP).
View Article and Find Full Text PDFSmall
January 2025
School of Chemistry, South China Normal University, Guangzhou, 510006, P. R. China.
Intrinsic low conductivity, poor structural stability, and narrow interlayer spacing limit the development of MnO in sodium-ion (Na) supercapacitors. This work constructs the hollow cubic Mn-PBA precursor through an ion-exchange process to in situ obtain a hollow cubic H-Ni-MnO composite with Ni doping and oxygen vacancies (O) via a self-oxidation strategy. Experiments and theoretical calculations show that the hollow nanostructure and the expanding interlayer spacing induced by Ni doping are beneficial for exposing more reactive sites, synergistically manipulating the Na transport pathways.
View Article and Find Full Text PDFAdv Mater
January 2025
Institute of Functional Nano & Soft Materials (FUNSOM), Jiangsu Key Laboratory of Carbon-Based Functional Materials and Devices, Soochow University, Suzhou, 215123, P. R. China.
The selective recycling of mixed plastic wastes with similar structural units is challenging. While heterogeneous catalysis shows potential for selective recycling, challenges such as complex mass transfer at multiphase interfaces and unclear catalytic mechanisms have slowed progress. In this study, a breakthrough in recycling mixed polyester wastes is introduced using heterogeneous photothermal catalysis.
View Article and Find Full Text PDFLangmuir
January 2025
Department of Chemistry and Centre for Advanced Studies in Chemistry, Panjab University, Chandigarh 160014, India.
Herein, we present a novel liquid crystal (LC)-based sensing platform utilizing microgel-stabilized Pickering LC droplets dispersed in water for simple and label-free detection of proteins in an aqueous environment. This could be achieved by tailoring the surface of 4-cyano-4'-pentylbiphenyl (5CB) LC droplets dispersed in aqueous medium through the interfacial adsorption of poly(-isopropylacrylamide) (PNIPAM) microgel particles, followed by the introduction of model surfactants, such as anionic sodium dodecyl sulfate and cationic dodecyltrimethylammonium bromide. These surfactant/microgel complex-coated LC droplets underwent a configurational transition from radial-to-bipolar under a polarized optical microscope, upon exposure to model proteins, namely bovine serum albumin and lysozyme.
View Article and Find Full Text PDFNat Commun
January 2025
State Key Laboratory of Urban Water Resource and Environment, School of Environment, Harbin Institute of Technology, Harbin, 150090, P. R. China.
Oil spill disasters lead to widespread and long-lasting social, economical, environmental and ecological impacts. Technical challenges remain for conventional static adsorption due to hydrodynamic instability under complex water-flow conditions, which results in low oil-capture efficiency, time delay and oil escape. To address this issue, we design a vortex-anchored filter inspired by the anatomy of deep-sea glass sponges (E.
View Article and Find Full Text PDFEnter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!