We demonstrate the existence of a cross Feshbach resonance by strongly driving a lower polariton mode and by monitoring in time the transmission of a short optical pulse at the energy of the upper polariton mode in a semiconductor microcavity. From the signatures of the optical resonance, strength, and sign of the energy shift, we attribute the origin of the scattering process between polariton modes with opposite circular polarization to a biexciton bound state. From this study, we infer the conditions required for a strong enhancement of the generation of entangled photon pairs.
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http://dx.doi.org/10.1103/PhysRevLett.122.047402 | DOI Listing |
J Chem Phys
September 2024
School of Physics, Dalian University of Technology, Dalian 116024, China.
In this paper, we investigate the Feshbach resonances of high partial waves and the influence of spin-spin (S-S) interaction on ultracold scattering processes. Taking the Na23- Rb87 system as an example, we plot the variations of weakly bound state energy and elastic scattering cross section with magnetic field and with collision energy. We find that the number of splittings in high partial wave Feshbach resonances does not strictly conform to the expected l + 1 (l is rotational angular momentum), and the deviation is attributed to the influence of bound states in other channels coupled by S-S interaction.
View Article and Find Full Text PDFPhys Chem Chem Phys
August 2024
Department of Mathematics, Scottish Church College, 1 & 3 Urquhart Square, Kolkata 700 006, India.
We present here a theoretical study of a new molecular ion species BeN, which has not been reported before. Using a good quality configuration interaction model, we first undertake a configuration interaction calculation of the molecular states to obtain the potential energy curves of several low lying states of BeN and the dipole and transition dipole moments of some of its states as a function of the internuclear distance. We find the ground state to be bound and of X Σ character having a shallow minimum at = 2.
View Article and Find Full Text PDFJ Chem Phys
September 2023
State Key Laboratory for Mesoscopic Physics and Frontiers Science Center for Nano-Optoelectronics, School of Physics, Peking University, Beijing 100871, China.
The quantum state-to-state rotationally inelastic quenching of N2O by colliding with a He atom is studied on an ab initio potential energy surface with N2O lying on its vibrational ground state. The cross sections for collision energies from 10-6-100 cm-1 and rate constants from 10-5-10 K are calculated employing the fully converged quantum close-coupling method for the quenching of the j = 1-6 rotational states of N2O. Numerous van der Waals shapes or Feshbach resonances are observed; the cross sections of different channels are found to follow the Wigner scaling law in the cold threshold regime and may intersect with each other.
View Article and Find Full Text PDFJ Phys Chem A
December 2023
Department of Physics, Indian Institute of Technology (Indian School of Mines), Dhanbad 826004, India.
Chem Sci
July 2023
State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Sciences Dalian Liaoning 116023 China
The signature of dynamics resonances was observed in the benchmark polyatomic F + CH/CHD reactions more than a decade ago; however, the dynamical origin of the resonances is still not clear due to the lack of reliable quantum dynamics studies on accurate potential energy surfaces. Here, we report a six-dimensional state-to-state quantum dynamics study on the F + CHD → HF + CD reaction on a highly accurate potential energy surface. Pronounced oscillatory structures are observed in the total and product rovibrational-state-resolved reaction probabilities.
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