Homochiral iron(ii)-based nanotubular metal phosphonates (R)- and (S)-[Fe(pemp)(H2O)2] [pemp2- = (R)- or (S)-(1-phenylethylamino)methylphosphonate] are reported showing metamagnetism at low temperature. The dehydrated product features coordinatively unsaturated and redox-active metal ion sites that enable it to strongly bind nitric oxide at room temperature.
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