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Electrochemically driven interfacial halogen bonding on self-assembled monolayers for anion detection. | LitMetric

Electrochemically driven interfacial halogen bonding on self-assembled monolayers for anion detection.

Chem Commun (Camb)

Laboratoire d'Electrochimie Moléculaire, UMR CNRS 7591, Université Paris Diderot, Sorbonne Paris Cité, 15 rue Jean-Antoine de Baïf, F-75205 Paris Cedex 13, France.

Published: February 2019

AI Article Synopsis

Article Abstract

Electrochemically driven interfacial halogen bonding between redox-active SAMs and halide anions was quantitatively studied for the first time. The halogen bond donor properties were switched on by electrochemically controlling the oxidation state of the adsorbates. Experimental data and simulation show high binding enhancement towards halide anions compared to homogeneous systems.

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Source
http://dx.doi.org/10.1039/c8cc08856jDOI Listing

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