Rutile TiO layers were formed on substrates of Ti-(0-10)at%Au alloys by a simple process of air oxidation, and their antibacterial activities were evaluated under visible-light irradiation (λ ≥ 400 nm). Au was introduced into the TiO layers on Ti-(1-10)at%Au alloys and existed as both metallic Au nanoparticles and dissolved Au ions. The TiO layers that formed on Ti-5at%Au and Ti-10at%Au alloys exhibited visible-light photocatalytic activity, that is, degradation of stearic acid and antibacterial activity against Escherichia coli. These visible-light activities were attributed to the surface plasmon resonance of metallic Au nanoparticles and the decrease in bandgap energy caused by dissolved Au ions. The formation of hydroxyl radicals observed under visible-light irradiation is attributable to antibacterial activity. From a cost perspective, a Ti-5at%Au alloy is more suitable as a substrate for the formation of a TiO layer with antibacterial properties than a Ti-10at%Au alloy. © 2019 Wiley Periodicals, Inc. J Biomed Mater Res Part A: 107A: 991-1000, 2019.
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http://dx.doi.org/10.1002/jbm.a.36624 | DOI Listing |
Talanta
December 2024
Chongqing Institute of Green and Intelligent Technology, Chinese Academy of Sciences, Chongqing, 400714, China. Electronic address:
The proliferation of micro/nanoplastics (MNPs) has emerged as a pivotal environmental issue, largely due to their potential for human exposure. Consequently, the development of sensitive and efficient detection methodologies is paramount for elucidating their environmental footprint. Here, we report a novel three-dimensional (3D) surface-enhanced Raman scattering (SERS) sensor, which integrate TiCT/TiO/WO semiconductor heterostructure, for the rapid and sensitive detection of MNPs in environmental matrices.
View Article and Find Full Text PDFSci Rep
December 2024
Centre of Advanced Research in Bionanoconjugates and Biopolymers, "Petru Poni" Institute of Macromolecular Chemistry, 41A, Grigore Ghica Voda Alley, 700487, Iasi, Romania.
One of the biggest issues of wide bandgap semiconductor use in photocatalytic wastewater treatment is the reusability of the material and avoiding the contamination of water with the material itself. In this paper, we report on a novel TiO aeromaterial (aero-TiO) consisting of hollow microtetrapods with ZnTiO inclusions. Atomic layer deposition has been used to obtain particles of unique shape allowing them to interlock thereby protecting the photocatalyst from erosion and damage when incorporated in active filters.
View Article and Find Full Text PDFACS Appl Mater Interfaces
December 2024
Central European Institute of Technology, Brno University of Technology, Purkynova 123, 612 00 Brno, Czech Republic.
The current study investigates and compares the biological effects of ultrathin conformal coatings of zirconium dioxide (ZrO) and vanadium pentoxide (VO) on osteoblastic MG-63 cells grown on TiO nanotube layers (TNTs). Coatings were achieved by the atomic layer deposition (ALD) technique. TNTs with average tube diameters of 15, 30, and 100 nm were fabricated on Ti substrates (via electrochemical anodization) and were used as primary substrates for the study.
View Article and Find Full Text PDFJ Colloid Interface Sci
December 2024
Key Laboratory of Functional Inorganic Material Chemistry, Ministry of Education of the People's Republic of China, Heilongjiang University, Harbin 150080, PR China. Electronic address:
Photocatalytically reducing CO into high-value-added chemical materials has surfaced as a viable strategy for harnessing solar energy and mitigating the greenhouse effect. But the inadequate separation of the photogenerated electron-hole pair remains a major obstacle to CO photoreduction. Constructing heterostructure photocatalysts with efficient interface charge transfer is a promising approach to solving the above problems.
View Article and Find Full Text PDFNanomaterials (Basel)
December 2024
Fort Hare Institute of Technology, University of Fort Hare, Private Bag X1314, Alice 5700, Eastern Cape, South Africa.
Energy generation and storage are critical challenges for developing economies due to rising populations and limited access to clean energy resources. Fossil fuels, commonly used for energy production, are costly and contribute to environmental pollution through greenhouse gas emissions. Quantum dot-sensitized solar cells (QDSSCs) offer a promising alternative due to their stability, low cost, and high-power conversion efficiency (PCE) compared to other third-generation solar cells.
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