Silica Aerogel composites are ultra-low density, highly porous foam-like materials that exhibit excellent thermal insulation and high strain recovery characteristics. In the present work, environment-friendly silica aerogel composites are fabricated using silica aerogel granules with bio based porcine-gelatin as the binding agent dissolved in water and by further drying the mix at sub-zero condition. This article focuses on improvement studies carried on the mold design and the manufacturing process to achieve better geometric compliance for the silica aerogel composites. It also presents contact angle measurements, compressive behavior under different cycles of loading, time dependent behavior and flexural response of the composites. The influence of additives, such as fumed silica and carbon nanotubes on mechanical properties of the composites is also deliberated. Water droplet contact angle experiments confirmed the ultra-hydrophobic nature of the composites. The mechanical properties were characterized under cyclic loading-unloading compression and three-point flexure tests. On successive compression in three consecutive load cycles, the strain and thickness recovery were found to decrease by around 30%. The flexural properties of the aerogel composites were investigated using it as the core covered by thin carbon composite face sheets. It was found that the flexural strength and the failure strain of this aerogel sandwich composites is approximately half of the conventional nomex honeycomb sandwich equivalent.
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http://dx.doi.org/10.3390/gels4010005 | DOI Listing |
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January 2025
Laboratory of Advanced Materials, Department of Chemistry, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, State Key Laboratory of Molecular Engineering of Polymers, Collaborative Innovation Center of Chemistry for Energy Materials, Fudan University, Shanghai, 200433, China.
Thermal management is a key link in improving energy utilization and preparing insulation materials with excellent performance is the core technological issue. Complex and irregular pore structures of insulation materials hinder the exploration of structure-property relationships and the further promotion of material performance. Ordered mesoporous silica (OMS) is a kind of porous material with ordered frameworks.
View Article and Find Full Text PDFNanomaterials (Basel)
January 2025
State Key Laboratory of High-Performance Civil Engineering Materials, Jiangsu Sobute New Materials Co., Ltd., Nanjing 210008, China.
A novel class of SiO aerogel-based resin composite with a self-formed foamy structure and an extremely low thermal conductivity, as well as excellent fire resistance, was fabricated via a room temperature and atmospheric pressure route. The self-formed foamy structure was achieved by utilizing SiO aerogel particles not only as a thermal insulative functional additive filler but also as nano-sized solid particles in a Picking emulsion system, adjusting the surface tension as a stabilizer at the interface between the two immiscible phases (liquid and air in this case). The results of foamy structure analyses via scanning electron microscopy, micro-CT, and N adsorption-desorption isotherms validate the successful generation of a micro-scale porous structure with the enhancement of the aerogel nano-scale solid particles at the wall as a stabilizer.
View Article and Find Full Text PDFGels
January 2025
Key Laboratory of Original Agro-Environmental Pollution Prevention and Control (Ministry of Agriculture and Rural Affairs (MARA)), Tianjin Key Laboratory of Agro-Environment and Agro-Product Safety, Agro-Environmental Protection Institute, MARA, Tianjin 300191, China.
To expand the applications of hydrophobic silica aerogels derived from rice husk ash (HSA) through simple traditional methods (without adding special materials or processes), this paper employs machine learning to establish mathematical models to identify optimal conditions for extracting water glass and investigates how preparation conditions and heat treatment temperatures affect properties such as the porosity and hydrophobicity of HSA. The results indicate that the decision tree regression model provides the most accurate predictions for the extraction rate and modulus of water glass. Notably, the water contact angle of HSA produced using nitric acid as a catalyst can reach as high as 159.
View Article and Find Full Text PDFCarbohydr Polym
March 2025
Key Laboratory of Organic Optoelectronics and Molecular Engineering of the Ministry of Education, Department of Chemistry, Tsinghua University, Beijing 100084, PR China. Electronic address:
High-performance solar interface evaporators provide a promising, sustainable, and cost-effective solution to the global freshwater crisis through seawater purification. However, achieving a delicate balance between maximizing the evaporation rate and ensuring continuous, stable, and durable operation presents a critical challenge. Herein, we present a biomimetic cellulose/polypyrrole-coated silica/graphene evaporator with self-assembled nanofiber networks and vertically aligned vessels for enhanced salt resistance.
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2025
Shenzhen Key Laboratory of Intelligent Robotics and Flexible Manufacturing Systems, Department of Mechanical and Energy Engineering, Southern University of Science and Technology, Shenzhen 518055, China.
This study presents the development of a solar-driven thermally regenerative electrochemical cell (STREC) for continuous power generation. Key innovations include dual-function carbon-based electrodes for efficient solar absorption and electrochemical reactions, a transparent and ultrainsulating silica aerogel to maximize solar spectrum transmission while minimizing heat loss, and a compact heat exchanger to recover heat from hot cell streams. Under 1 sun conditions, the STREC achieves a power density of 912.
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