The acoustic properties of the silica aerogel (SA) granules of various sizes from 0.50 to 3.35 mm, distributed into six groups of nominal sizes and measured via a two-microphone impedance tube, are presented. The absorption coefficients of the SA granules were evaluated at ultra- to super-low frequency range from 50⁻1600 Hz. It was observed that nominal SA granules with sizes of 1.2 mm (AG2) and 1.7 mm (AG3) displayed the best absorption coefficients. When tested with granules filled at 5 cm depth, AG2 and AG3 absorption coefficients peaked at 980 Hz with values of 0.86 and 0.81, respectively. A novel approach to measure transmission loss (TL) by using "inferential" principle is presented. This novel method, named "Inferential Transmission Loss Method" (InTLM), revealed that the average TL, TL for both AG2 and AG3 SA granules was 14.83 dB and 15.35 dB, respectively. Gelatin silica aerogels doped with sodium dodecyl sulfate (GSA⁻SDS) composites comprising of 1.2 mm (GSA⁻AG2) and 1.7 mm (GSA⁻AG3) granules of various configurations were fabricated and evaluated for absorption coefficients and TL with known traditional acoustic panels. The results showed that GSA⁻AG3 had a better absorption coefficient over other configurations for the same corresponding thickness reaching the peak of 0.6 from 1300 to 1450 Hz with TL between 10.7 and 20.3 decibels. The four-layered GSA⁻AG2 and GSA⁻AG3 composites showed exceptionally high absorption from 500 to 800 Hz suitable for narrow band applications. Lastly, the "InTLM" was matched with the sound meter measurements, with high accuracy between 0.3 and 3.2 dB for low-frequency testing (50⁻1600 Hz).
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http://dx.doi.org/10.3390/gels2010011 | DOI Listing |
Biomaterials
January 2025
Lab of Molecular Imaging and Translational Medicine (MITM), Engineering Research Center of Molecular and Neuro Imaging, Ministry of Education, School of Life Science and Technology, Xidian University & International Joint Research Center for Advanced Medical Imaging and Intelligent Diagnosis and Treatment, Xi'an, Shaanxi, 710126, China. Electronic address:
The secondary near-infrared region (NIR-II) fluorescence imaging-guided photothermal therapy (PTT) offers a noninvasive and light-controllable treatment option for deep-seated cancers. However, the development of NIR-II photothermal agents (NIR-II PTAs) that possess the desired properties of high molar absorption coefficient (ε), fluorescence quantum yield (QY), and photothermal conversion efficiency (PCE) remain a challenge due to the contradiction between radiative and nonradiative processes. Herein, we propose a novel side-chain heteroatom substitution engineering strategy to simultaneously enhance ε, QY, and PCE by modifying the molecular planarity.
View Article and Find Full Text PDFNanomedicine (Lond)
January 2025
Jiangsu Key Laboratory of New Drug Research and Clinical Pharmacy, Xuzhou Medical University, Xuzhou, China.
Photodynamic therapy (PDT) involves the activation of photosensitizers (PSs) by visible laser light at the target site to catalyze the production of reactive oxygen species, resulting in tumor cell death and blood vessel closure. The efficacy of PDT depends on the PSs, the amount of oxygen, and the intensity of the excitation laser. PSs have been extensively researched, and great efforts have been made to develop an ideal photosensitizer.
View Article and Find Full Text PDFHigh-resolution optical diagnostics in the short wavelength infrared (SWIR II) region have gained significant attention in medical research, showing great potential for tissue spectroscopy and visualization due to the region's low water absorption and scattering coefficients. However, high-beam-quality sources covering an entire spectral range are limited. This paper presents the development of a femtosecond Cr:ZnSe laser with a 2.
View Article and Find Full Text PDFThe intrinsic spontaneous and piezoelectric polarizations of GaN lead to the formation of triangular wells and barriers, resulting in the manifestation of chaotic transport models in GaN quantum well intersubband transition (ISBT) infrared detectors and giving rise to various adverse effects. The APSYS software was utilized to construct a novel GaN quantum well ISBT infrared detector in this study. By endeavoring to modify the quantum well structure, our objective was to precisely adjust the energy level of the first excited state (E1) to align with the apex of the triangular barrier.
View Article and Find Full Text PDFMetal halide perovskites have unique luminescent properties that make them an attractive alternative for high quality light-emitting devices. However, the poor stability of perovskites with many defects and the long cycle time for the preparation of perovskite nanocomposites have hindered their production and application. Here, we prepared the perovskite mesostructures by embedding MAPbBr nanocrystals in the mesopores on the surface of silica nanospheres and mixing the nanospheres with silver nanowires and poly(methyl methacrylate) (PMMA), and further explored their optical properties.
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