Carbon monoxide (CO) is a toxic gas with potential for detriment to spaceflight operations. An analytical model was developed to investigate if a maximum CO contamination of 1 ppm in the oxygen (O₂) supply reached dangerous levels during extravehicular activity (EVA). Occupational monitoring pre- and postsuited exposures provided supplementary data for review. The analytical model estimated O₂ and CO concentrations in the extravehicular mobility unit (EMU) based on O₂ and CO flow rates into and out of the system. The model was based on 3 h of prebreathe at 15.2 psia, 8 h of EVA at 4.3 psia, and 1 h at 15.2 psia for suit doffing. The Coburn-Forster-Kane equation was used to calculate crewmember carboxyhemoglobin saturation (COHb%) as a function of time. Monitoring of hemoglobin CO saturation (Sco) with a CO-oximeter was conducted pre- and post-EVA during operations on the International Space Station and in ground-based analog environments. The model predicted a maximum P in the EMU of 0.061 mmHg and a maximum crewmember COHb% of 2.1%. Operational Sco measurements in mean ± SD during ground-based analog testing were 0.7% ± 1.8% pretest and 0.5% ± 1.5% posttest. Sco values on the ISS were 1.5% ± 0.7% pre-EVA and 1.1% ± 0.3% post-EVA. The model predicted that astronauts are not exposed to toxic levels of CO during EVA and operational measurements did not show significant differences between Sco levels between pre- and post-EVA.
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http://dx.doi.org/10.3357/AMHP.5220.2019 | DOI Listing |
Nat Commun
January 2025
Shenzhen Key Laboratory of Ecological Remediation and Carbon Sequestration, Institute of Environment and Ecology, Tsinghua Shenzhen International Graduate School, Tsinghua University, Shenzhen, China.
Monitoring methane (CH) emissions from terrestrial ecosystems is essential for assessing the relative contributions of natural and anthropogenic factors leading to climate change and shaping global climate goals. Fires are a significant source of atmospheric CH, with the increasing frequency of megafires amplifying their impact. Global fire emissions exhibit large spatiotemporal variations, making the magnitude and dynamics difficult to characterize accurately.
View Article and Find Full Text PDFGlob Chang Biol
January 2025
Department of Environmental and Biological Sciences, Faculty of Science, Forestry and Technology, University of Eastern Finland, Kuopio, Finland.
Primary and secondary atmospheric pollutants, including carbon monoxide (CO), carbon dioxide (CO), nitrogen oxides (NO), ozone (O), sulphur dioxide (SO) and particulate matter (PM/PM) with associated heavy metals (HMs) and micro- and nanoplastics (MPs/NPs), have the potential to influence and alter interspecific interactions involving insects that are responsible for providing essential ecosystem services (ESs). Given that insects rely on olfactory cues for vital processes such as locating mates, food sources and oviposition sites, volatile organic compounds (VOCs) are of paramount importance in interactions involving insects. While gaseous pollutants reduce the lifespan of individual compounds that act as olfactory cues, gaseous and particulate pollutants can alter their biosynthesis and emission and exert a direct effect on the olfactory system of insects.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
January 2025
Università di Milano-Bicocca, Dipartimento di Scienza dei Materiali, via Cozzi 55, 20125, Milano, ITALY.
Confined single metal atoms in graphene-based materials have proven to be excellent catalysts for several reactions and promising gas sensing systems. However, whether the chemical activity arises from the specific type of metal atom or is a direct consequence of the confinement itself remains unclear. In this work, through a combined density functional theory and experimental surface science study, we address this question by investigating Co and Ni single atoms embedded in graphene (Gr) on a Ni(111) support.
View Article and Find Full Text PDFSmall
January 2025
Materials Physics and Applications Division, Los Alamos National Laboratory, Los Alamos, NM, 87545, USA.
The atomic dispersion of nickel in Ni-N-C catalysts is key for the selective generation of carbon monoxide through the electrochemical carbon dioxide reduction reaction (CORR). Herein, the study reports a highly selective, atomically dispersed Ni-N-C catalyst with reduced Ni loading compared to previous reports. Extensive materials characterization fails to detect Ni crystalline phases, reveals the highest concentration of atomically dispersed Ni metal, and confirms the presence of the proposed Ni-N active site at this reduced loading.
View Article and Find Full Text PDFIntern Emerg Med
January 2025
The Toxikon Consortium, 1950 West Polk St, 7th Floor, Chicago, IL, 60612, USA.
Carbon monoxide (CO) poisoning continues to result in hospitalization and mortality. We sought to analyze risk factors associated with inpatient admission for CO poisoning. Retrospective study of the US National Inpatient Sample (NIS) database.
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