Iron carbide (Fe₃C) is a ceramic magnetic material with high potential for applications in different fields, including catalysis, medicine imaging, coatings, and sensors. Despite its interesting properties, it is still somehow largely unexplored, probably due to challenging synthetic conditions. In this contribution, we present a sol-gel-based method that allows preparing different Fe₃C@C nanocomposites with tailored properties for specific applications, in particular, we have focused on and discussed potential uses for adsorption of noxious gas and waste removal. Nanocomposites were prepared using readily available and "green" sources, such as urea, simple and complex sugars, and chitosan. The nanocomposite prepared from chitosan was found to be more efficient for CO₂ uptake, while the sample synthetized from cellulose had optimal capability for dye absorption and waste oil removal from water.
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http://dx.doi.org/10.3390/ma12020323 | DOI Listing |
Rev Sci Instrum
May 2021
Department of Earth Sciences, University College London, Gower Street, London WC1E 6BT, United Kingdom.
A new "solid-state" oxygen buffering reaction (WC-COW), WC + 1/2O ⇌ CO + W, is presented. At atmospheric pressure, the oxygen fugacity in equilibrium with this buffer is approximated in the range of 600-1200 °C by logf =1.53-21008TK±0.
View Article and Find Full Text PDFMaterials (Basel)
January 2019
School of Biological and Chemical Sciences, Chemistry Department, Queen Mary University of London, Mile End Road, London E1 4NS, UK.
Iron carbide (Fe₃C) is a ceramic magnetic material with high potential for applications in different fields, including catalysis, medicine imaging, coatings, and sensors. Despite its interesting properties, it is still somehow largely unexplored, probably due to challenging synthetic conditions. In this contribution, we present a sol-gel-based method that allows preparing different Fe₃C@C nanocomposites with tailored properties for specific applications, in particular, we have focused on and discussed potential uses for adsorption of noxious gas and waste removal.
View Article and Find Full Text PDFChemistry
April 2018
Max Planck Institute of Colloids and Interfaces, Colloid Department, Am Mühlenberg 1, 14476, Potsdam, Germany.
Fe N and Fe C nanocomposites have a wide range of applications thanks to their ceramic nature, magnetic properties, conductivity and catalytic activity, just to cite some. In many fields optimal performances are ensured by crystallinity, homogeneity and hierarchical organization. In the present paper, crystalline, magnetic and well-defined nanofibres of iron nitride and iron carbide/carbon nanocomposite with tunable composition and size were prepared via electrospinning.
View Article and Find Full Text PDFChemphyschem
February 2017
Nanoengineering Research Group, Centre for Mechanical Technology and Automation (TEMA), Department of Mechanical Engineering, University of Aveiro, 3810-193, Aveiro, Portugal.
This study highlights that Fe additives offer better catalytic properties than carbon, Fe-C (iron carbide/carbon composites), and Fe-Mg (Mg FeH ) additives for the low-temperature dehydrogenation of magnesium hydride. The in situ X-ray diffraction measurements prove the formation of a Mg FeH phase in iron additive loaded MgH . Nonetheless, differential scanning calorimetry data suggest that this Mg FeH phase does not have any influence on dehydrogenation properties of MgH .
View Article and Find Full Text PDFJ Am Chem Soc
November 2010
Fukui Institute for Fundamental Chemistry, Kyoto University, Kyoto 606-8103, Japan.
The mechanism and kinetics of single-walled carbon nanotube (SWNT) nucleation from Fe- and Ni-carbide nanoparticle precursors have been investigated using quantum chemical molecular dynamics (QM/MD) methods. The dependence of the nucleation mechanism and its kinetics on environmental factors, including temperature and metal-carbide carbon concentration, has also been elucidated. It was observed that SWNT nucleation occurred via three distinct stages, viz.
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