Blue perovskite light-emitting diodes: progress, challenges and future directions.

Nanoscale

Department of Physics, Chemistry and Biology (IFM), Linköping University, Linköping 58183, Sweden.

Published: January 2019

Metal halide perovskites have excellent optical and electrical properties and can be easily processed via low-cost solution-based techniques like blade-coating and inkjet printing, promising a bright future for various optoelectronic applications. Recently, encouraging progress has been made in perovskite light-emitting diodes (PeLEDs). Green, red, and near-infrared PeLEDs have achieved high external quantum efficiencies of more than 20%. However, as historically blue electroluminescence remains challenging in all previous LED technologies, we are witnessing a similar case with the development of blue PeLEDs, an essential part of displays and solid-state lighting, which lag far behind those of their counterparts. Herein, we review the recent progress of blue PeLEDs and discuss the main challenges including colour instability, poor photoluminescence efficiency and emission quenching by interlayers. Future directions are provided to facilitate the development of efficient blue PeLEDs.

Download full-text PDF

Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC6369678PMC
http://dx.doi.org/10.1039/c8nr09885aDOI Listing

Publication Analysis

Top Keywords

blue peleds
12
perovskite light-emitting
8
light-emitting diodes
8
future directions
8
blue
5
peleds
5
blue perovskite
4
diodes progress
4
progress challenges
4
challenges future
4

Similar Publications

Strongly Anchored Dion-Jacobson Perovskite for Efficient Blue Light-Emitting Diodes.

Nano Lett

January 2025

State Key Laboratory of Solidification Processing, Center for Nano Energy Materials, School of Materials Science and Engineering, Northwestern Polytechnical University and Shaanxi Joint Laboratory of Graphene (NPU), Xi'an 710072, P. R. China.

Dion-Jacobson (DJ) perovskites are promising alternatives for Ruddlesden-Popper (RP) perovskites to fabricate blue perovskite light-emitting diodes (PeLEDs) due to their favorable structural and charge properties. However, the relatively weak hydrogen bond between the bridging diammonium group and perovskite poses huge challenges for regulating crystallization and defect density, leading to an undesirable film quality and device performance. Herein, we report the successful optimization of DJ perovskite films by introducing a new type of cesium octafluoroadipate (CsOFAA) precursor, which could strongly anchor the perovskite through coordination bonds and halogen-halogen bonds.

View Article and Find Full Text PDF

Non-Conjugated Gridized Nanopolymers as an Efficient Hole-Transport Material for Blue Perovskite Light-Emitting Diodes.

Small

December 2024

Frontiers Science Center for Flexible Electronics (FSCFE), MIIT Key Laboratory of Flexible Electronics (KLoFE), Northwestern Polytechnical University, Xi'an, 710072, China.

Despite the remarkable advancements in perovskite light-emitting diode (PeLED) technology, the development of blue PeLEDs has lagged. The primary bottleneck lies in the difficulty of finding hole transport materials (HTMs) that can both match the energy levels of blue perovskite materials and exhibit efficient hole transport performance. Herein, a novel non-conjugated polyethylene carbazole-based polymer (P-AGCz) is developed that has excellent solution processability and serves as an efficient dopant-free HTM for PeLEDs.

View Article and Find Full Text PDF

Lattice Stabilized and Emission Tunable Pure-Bromide Quasi-2D Perovskite for Air-Processed Blue Light-Emitting Diodes.

Adv Sci (Weinh)

December 2024

State Key Laboratory of Solidification Processing, Center for Nano Energy Materials, School of Materials Science and Engineering, Northwestern Polytechnical University and Shaanxi Joint Laboratory of Graphene (NPU), Xi'an, 710072, P. R. China.

Realizing air-processed blue halide perovskite films with tailored emission is significant for promoting the commercialization of perovskite light-emitting diodes (PeLEDs). However, the intrinsically inferior thermodynamic stability and laborious crystallization kinetics control under humidity interference limit the fabrication of blue perovskite emitters in ambient air. Here, air-processed pure-bromide quasi-2D blue perovskite films are achieved with stabilized lattice and tunable emission by interstitial doping of trivalent metallic cations.

View Article and Find Full Text PDF

Nondestructive halide exchange via S2-like mechanism for efficient blue perovskite light-emitting diodes.

Nat Commun

December 2024

Macao Institute of Materials Science and Engineering (MIMSE), Faculty of Innovation Engineering, Macau University of Science and Technology, Taipa, Macao, China.

Article Synopsis
  • Blue perovskite light-emitting diodes (PeLEDs) face challenges due to difficult production of high-quality mixed-halide perovskites with wide optical bandgaps, leading to high defect density.
  • A new strategy for nondestructive in-situ halide exchange helps create high-quality blue perovskites with low trap density by using long alkyl chain chloride in chloroform post-treatment.
  • This method improves efficiency in PeLEDs across the blue spectrum, achieving external quantum efficiencies of 23.6% (sky-blue), 20.9% (pure-blue), and 15.0% (deep-blue) emissions.
View Article and Find Full Text PDF

The halide postdeposition treatment technique is a widely used strategy for mitigating defects in perovskite. However, when applied to mixed-halide perovskites, it often leads to surface and internal halide heterogeneity, which compromises luminescence performance and spectral stability. In this work, blue mixed-halide 3D perovskites are engineered with acetate (Ac⁻)-rich surfaces to optimize the post-treatment process and achieve halide homogeneity.

View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!