Metal halide perovskites have excellent optical and electrical properties and can be easily processed via low-cost solution-based techniques like blade-coating and inkjet printing, promising a bright future for various optoelectronic applications. Recently, encouraging progress has been made in perovskite light-emitting diodes (PeLEDs). Green, red, and near-infrared PeLEDs have achieved high external quantum efficiencies of more than 20%. However, as historically blue electroluminescence remains challenging in all previous LED technologies, we are witnessing a similar case with the development of blue PeLEDs, an essential part of displays and solid-state lighting, which lag far behind those of their counterparts. Herein, we review the recent progress of blue PeLEDs and discuss the main challenges including colour instability, poor photoluminescence efficiency and emission quenching by interlayers. Future directions are provided to facilitate the development of efficient blue PeLEDs.
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http://dx.doi.org/10.1039/c8nr09885a | DOI Listing |
Nano Lett
January 2025
State Key Laboratory of Solidification Processing, Center for Nano Energy Materials, School of Materials Science and Engineering, Northwestern Polytechnical University and Shaanxi Joint Laboratory of Graphene (NPU), Xi'an 710072, P. R. China.
Dion-Jacobson (DJ) perovskites are promising alternatives for Ruddlesden-Popper (RP) perovskites to fabricate blue perovskite light-emitting diodes (PeLEDs) due to their favorable structural and charge properties. However, the relatively weak hydrogen bond between the bridging diammonium group and perovskite poses huge challenges for regulating crystallization and defect density, leading to an undesirable film quality and device performance. Herein, we report the successful optimization of DJ perovskite films by introducing a new type of cesium octafluoroadipate (CsOFAA) precursor, which could strongly anchor the perovskite through coordination bonds and halogen-halogen bonds.
View Article and Find Full Text PDFSmall
December 2024
Frontiers Science Center for Flexible Electronics (FSCFE), MIIT Key Laboratory of Flexible Electronics (KLoFE), Northwestern Polytechnical University, Xi'an, 710072, China.
Despite the remarkable advancements in perovskite light-emitting diode (PeLED) technology, the development of blue PeLEDs has lagged. The primary bottleneck lies in the difficulty of finding hole transport materials (HTMs) that can both match the energy levels of blue perovskite materials and exhibit efficient hole transport performance. Herein, a novel non-conjugated polyethylene carbazole-based polymer (P-AGCz) is developed that has excellent solution processability and serves as an efficient dopant-free HTM for PeLEDs.
View Article and Find Full Text PDFAdv Sci (Weinh)
December 2024
State Key Laboratory of Solidification Processing, Center for Nano Energy Materials, School of Materials Science and Engineering, Northwestern Polytechnical University and Shaanxi Joint Laboratory of Graphene (NPU), Xi'an, 710072, P. R. China.
Realizing air-processed blue halide perovskite films with tailored emission is significant for promoting the commercialization of perovskite light-emitting diodes (PeLEDs). However, the intrinsically inferior thermodynamic stability and laborious crystallization kinetics control under humidity interference limit the fabrication of blue perovskite emitters in ambient air. Here, air-processed pure-bromide quasi-2D blue perovskite films are achieved with stabilized lattice and tunable emission by interstitial doping of trivalent metallic cations.
View Article and Find Full Text PDFNat Commun
December 2024
Macao Institute of Materials Science and Engineering (MIMSE), Faculty of Innovation Engineering, Macau University of Science and Technology, Taipa, Macao, China.
Adv Mater
December 2024
Department of Electronic Engineering, The Chinese University of Hong Kong, Hong Kong, SAR, China.
The halide postdeposition treatment technique is a widely used strategy for mitigating defects in perovskite. However, when applied to mixed-halide perovskites, it often leads to surface and internal halide heterogeneity, which compromises luminescence performance and spectral stability. In this work, blue mixed-halide 3D perovskites are engineered with acetate (Ac⁻)-rich surfaces to optimize the post-treatment process and achieve halide homogeneity.
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