A series of dicationic ionic liquids (ILs) including [C(MIM)][PF], [C(MIM)][PF], [C(MIM)][PF] and [C(PYR)][PF] were synthesized. Their thermal stability and melting points were analysed. It was found that dicationic ILs presented important implications in the design of homogeneous and heterogeneous system with water. A homogeneous system of dicationic ILs with water could be formed at a relatively high temperature and then a heterogeneous system was formed when the solution was cooled to a low temperature. The ILs recovered by altering the temperature were obtained in high percentage yields of [C(MIM)][PF] (97.6%), [C(MIM)][PF] (97.3%), [C(MIM)][PF] (98.0%) and [C(PYR)][PF] (94.2%). On the other hand, [C(MIM)][PF] and [C(MIM)][PF] exhibited good solubility in acetonitrile and acetone. A homogeneous system could be achieved with imidazolium-based ILs with a relatively low amount of water and acetonitrile at room temperature. All of the properties of dicationic ILs have a strong correlation with the nature of dications, the linkage chain and the symmetry of dications. Dicationic ILs may provide a new opportunity for some specific applications in order to enable the effective separation and isolation of products.
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