We study the formation of periodic nanostructures on Ag-AgCl thin films by irradiating s-polarized laser beams at different incident angles. A theoretical model is proposed to describe the formation of the structures based on interference of the incident beam and TE mode propagating in an AgCl slab waveguide. The line-space of periodic nanostructures on Ag-AgCl thin film can be manipulated by changing the incident angle and wavelength of the laser beam. The scattering and diffraction pattern of a periodic nanostructure during laser irradiation provides useful information about the structure's surface morphology. The periodic nanostructures formed on Ag-AgCl thin films are anisotropic structures.
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http://dx.doi.org/10.1364/AO.57.010355 | DOI Listing |
Anal Chem
November 2024
Radiochemistry Program, Department of Chemistry and Biochemistry, University of Nevada, Las Vegas, Las Vegas, Nevada 89154, United States.
Spectroelectrochemistry (SEC) is a powerful technique that enables a variety of redox properties to be studied, including formal potential (), thermodynamic values (Δ, Δ, Δ), diffusion coefficient (), electron transfer stoichiometry (), and others. SEC requires an electrode which light can pass through while maintaining sufficient electrical conductivity. This has been traditionally composed of metal or metal oxide films atop transparent substrates like glass, quartz, or metallic mesh.
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October 2024
Department of Chemistry, Federal University of São Carlos, Rod. Washington Luiz, Km 235, CEP, 13565-905, São Carlos-SP, Brazil.
The necessity of new methods to substitute the Haber-Bosch process in the NH synthesis, generating fewer greenhouse gases, and dispensing less energy, drove the investigation of the photoelectrocatalytic approach in the N reduction reaction (N2RR). For that, this work presents the synthesis and characterization of the layered CZTSSe/CdS/TiO photocathode decorated with Pt nanoparticles for application in NH production using the photoelectrocatalysis technique. The CZTSSe/CdS/TiO-Pt characterization showed a well-designed and stable photocatalyst synthesized layer by layer with an important contribution of the Pt nanoparticles for the catalyst performance, improving the photocurrent density and the charge transfer.
View Article and Find Full Text PDFRSC Adv
September 2024
Laboratory of Physical Chemistry and Biotechnology of Biomolecules and Materials, Faculty of Sciences and Technology, Hassan II University of Casablanca Mohammedia 20650 Morocco
Potentiostatic and electrochemical impedance spectroscopy (EIS) measurements were recorded to study the nucleation and growth mechanisms of electrodeposited CuNiSnS (CNTS) thin films from aqueous solution at different applied potentials. The electrodeposition process of Cu-Ni-Sn-S precursors were studied using cyclic voltammetry and chronoamperometry techniques. The nucleation and growth mechanism of these films was found to follow a three-dimensional progressive nucleation limited by diffusion-controlled growth.
View Article and Find Full Text PDFNanoscale
August 2024
Centre for Plasma and Laser Engineering, Institute of Fluid-Flow Machinery, Polish Academy of Sciences, Fiszera 14 Street, 80-231 Gdańsk, Poland.
Differences between photoelectrochemical and electrochemical activity were thoroughly investigated for the oxygen evolution reaction mediated by AgS deposited on two types of ordered titania substrates. Titanium dioxide nanotubes were fabricated by anodization of magnetron sputtered Ti films on ITO-coated glass substrates or directly from Ti foil. Further, AgS deposition on the nanotubes was carried out using successive ionic layer adsorption and reaction, known as SILAR, with 5, 25, and 45 cycles performed.
View Article and Find Full Text PDFFood Chem
November 2024
Institute of Biochemical and Biomedical Engineering, Department of Chemical Engineering and Biotechnology, National Taipei University of Technology, Taipei 10608, Taiwan.
Bisphenols threaten human health and sensitive detection is crucial. The present study aims to develop ternary composites of copper metal-organic framework (Cu-MOF) with AuAg microstructures. The composite structure was formed by a galvanic displacement reaction and confirmed using SEM.
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