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Ruthenium-based olefin metathesis catalysts with monodentate unsymmetrical NHC ligands. | LitMetric

Ruthenium-based olefin metathesis catalysts with monodentate unsymmetrical NHC ligands.

Beilstein J Org Chem

Dipartimento di Chimica e Biologia "Adolfo Zambelli", Università di Salerno, Via Giovanni Paolo II 132, I-84084 Fisciano, Salerno, Italy.

Published: December 2018

An overview on the catalytic properties of ruthenium complexes for olefin metathesis bearing monodentate unsymmetrical N-heterocyclic diaminocarbene ligands is provided. The non-symmetric nature of these NHC architectures strongly influences activity and selectivity of the resulting catalysts. The main achievements that have been accomplished in significant areas of olefin metathesis up to the current state of research are discussed.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC6317415PMC
http://dx.doi.org/10.3762/bjoc.14.292DOI Listing

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