Recent Advances in the Use of Black TiO for Production of Hydrogen and Other Solar Fuels.

Chemphyschem

Associate Professor S. Sartori, Department of Technology Systems, University of Oslo, NO-2027, Kjeller, Norway.

Published: May 2019

AI Article Synopsis

  • Black TiO is gaining attention as a promising photocatalyst due to its unique surface defects and Ti species that enhance its catalytic activity.
  • Recent studies focus on its applications in metal-free hydrogen production, CO photoreduction, and nitrogen photofixation, showcasing the material's versatility.
  • The article emphasizes the need for further research to explore the structure/property relationships and improve understanding of light absorption mechanisms in black TiO, particularly for solar fuels production.

Article Abstract

Black TiO has emerged as one of the most promising photocatalysts recently discovered. The reason behind its catalytic activity is considered to be due to the presence of defects and Ti species at the surface of black TiO nanostructures, which are crucial for its diverse applications. Moreover, disordered/crystalline surface layers and bulk regions have been identified and appear to influence the intrinsic properties of the material. Here, we present the latest studies on the use of black TiO for metal free hydrogen production, as well as for CO photoreduction and N photofixation. After highlighting the structure/property relations, we conclude with some critical questions and suggest further topics of research in order to better understand the underlying mechanisms of light absorption in black TiO , especially towards solar fuels production.

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Source
http://dx.doi.org/10.1002/cphc.201801094DOI Listing

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