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Ligand-modulated ring-expansion. | LitMetric

Ligand-modulated ring-expansion.

Chem Commun (Camb)

Department of Chemistry, University of British Columbia, 2036 Main Mall, Vancouver, British Columbia V6T 1Z1, Canada.

Published: January 2019

An unstrained palladium-containing macrocycle was expanded by a ring-opening metathesis strategy. This reaction was driven by coordination of a bulky ligand, 2,6-lutidine, to the palladium center, enabling a monometallic macrocycle to transform into a bimetallic dimeric macrocycle.

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Source
http://dx.doi.org/10.1039/c8cc09710kDOI Listing

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