Application of palladium-modified zeolite for prolonging post-harvest shelf life of banana.

Background: The marketability of banana is limited by the rapid rate of ripening. However, the traditional post-harvest technologies may not be desirable. The aim of this study was to investigate the potential of a reusable material for the food preservation industry.

Results: The nanocomposite-based palladium (Pd)-modified zeolite (Pd/zeolite) was prepared by impregnating Pd into zeolite. Pd/zeolite had a Brunauer-Emmett-Teller dinitrogen specific surface area of 475 m g with crystal structure similar to Y-zeolite. Transmission electron microscopy images showed the dispersion of Pd particles over the multi-pore zeolite support. Pd/zeolite uniquely acted as an adsorbent and a catalyst and was able to remove ethylene even after reaching breakthrough point. To prove Pd/zeolite is reusable, a 99 ± 0.8% ethylene removal efficiency still remained even after five consecutive cycles with repeated use of Pd/zeolite. The presence of Pd/zeolite significantly decreased the ethylene concentration during 18 days of storage at 20 ± 2 °C.

Conclusions: Pd/zeolite could delay the ripening of banana and improve its firmness and the peel color significantly. Findings indicated that the as-prepared Pd/zeolite is an effective adsorbent/catalyst with high potential for practical application in ethylene removal, especially for the post-harvest period. © 2019 Society of Chemical Industry.