Although a number of synthetic methodologies have been developed to prepare stable polycyclic aromatic hydrocarbons (PAHs), much less research has been devoted to functionalizing the peripheries of molecules to tune the self-assembly ability or introduce functional groups without altering their photophysical properties. Herein, we report twisted "X"-shaped molecules prepared through annulation of hexacene with benzoanthracene on the zigzag edge, and an investigation of their photophysical properties and self-assembly properties. The shape-complementary "X"-shaped molecules prefer to dimerize, while the π-extension would lead to one-dimensional π-stacking. Our findings give some insights into the design of stable PAHs without disturbing the electronic structures.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1002/asia.201801915 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
'Neither here nor there'? Meiofauna as an effective tool to evaluate the impacts of the 2019 mysterious oil spill in a Northeast Brazil coral reef.
Mar Pollut Bull
January 2025
Universidade Federal de Pernambuco, Programa de Pós-Graduação em Biologia Animal, Center for Biosciences, Av. Prof. Morais Rêgo s/n, Recife, Pernambuco 50670-420, Brazil; Universidade Federal de Pernambuco, Department of Zoology, Center for Biosciences, Av. Prof. Morais Rêgo s/n, Recife, Pernambuco 50670-420, Brazil. Electronic address:
During the last half of 2019, the Northeast coast of Brazil suffered from an extensive oil spill of unknown origin, and marine organisms in those areas were subjected to significant impacts. In situations like this, the contaminant effects can persist for varying periods. Oil contaminants, such as polycyclic aromatic hydrocarbons (PAHs), generally reduce taxa's abundance and diversity in benthic communities in areas with greater exposure to chemical components.
View Article and Find Full Text PDFPotential emission risks of organic compounds from cement kilns.
J Hazard Mater
January 2025
State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China; College of Resource and Environment, University of Chinese Academy of Sciences, Beijing 100049, China; Jianghan University, Wuhan 430056, China.
The extensive application of cement kiln industry results in substantial stack gas emissions, posing a potential risk of discharging organic pollutants. Cement industry is not considered as a primary contributor to persistent organic pollutants like polychlorinated dibenzo-p-dioxins and furans (PCDD/Fs), owing to its extremely low emission factor. However, knowledge on the previously unrecognized chemicals that may possess higher emission factors from cement industry is lacking.
View Article and Find Full Text PDFCurrent level, sources, and risk of human exposure to PAHs, PBDEs and PCBs in South American outdoor air: A critical review.
Environ Res
January 2025
Institute of Science and Technology, São Paulo State University (UNESP), Av. Três de Março, 511, Alto da Boa Vista, 18087-180 Sorocaba, SP, Brazil. Electronic address:
This study provides comprehensive overview of the current level, sources and human exposure risk to hazardous polycyclic aromatic hydrocarbons (PAHs), polybrominated diphenyl ethers (PBDEs), and polychlorinated biphenyls (PCBs) in South American outdoor air. Research documents were obtainable for only 6 countries within the target period (2014 - 2024). For all contaminants, urban concentrations exceeded that of rural/remote locations.
View Article and Find Full Text PDFAirborne particulate matter inhalation bioaccessibility: A review of methodological aspects.
Chem Biol Interact
January 2025
Department of Environment and Planning, Centre for Environmental and Marine Studies, University of Aveiro, 3810-193 Aveiro, Portugal. Electronic address:
Research has consistently linked exposure to particulate matter (PM) with adverse health outcomes, including cardiovascular and pulmonary morbidity and mortality. Understanding the mechanisms by which PM leads to these effects on human health is crucial for developing effective mitigation strategies. One aspect of PM research that has gained increased attention in the past few years is the bioaccessibility of inhaled PM-bound pollutants that have potential to cause adverse health effects.
View Article and Find Full Text PDFTreatment of polycyclic aromatic hydrocarbons (PAHs) and polychlorinated biphenyls (PCBs) in stormwater using polishing columns with biochar and granular activated carbon.
Chemosphere
January 2025
Department of Civil and Environmental Engineering, University of Maryland, College Park, MD, 20742, USA. Electronic address:
Polycyclic Aromatic Hydrocarbons (PAHs) and Polychlorinated Biphenyls (PCBs) are recalcitrant organic pollutants often detected in stormwater. Various stormwater control measures (SCMs) can remove PAHs and PCBs by filtration, adsorption, and biodegradation. However, dissolved PAHs and PCBs remain present in the treated outflow of SCMs.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!