AI Article Synopsis
- A new method for creating benzo[b]phospholes- and benzo[b]siloles-fused pyrenes using transition metal-catalyzed C-H bond activation is presented.
- The compounds produced were thoroughly analyzed and characterized, including the use of X-ray diffraction techniques.
- A combination of experimental and theoretical work indicates that the presence of heteroatoms and their arrangement significantly influence the compounds' optical and redox properties.
Article Abstract
A new synthetic route toward the synthesis of benzo[b]phospholes- and benzo[b]siloles-fused pyrenes using a transition metal-catalyzed C-H bond activation is described. The compounds were fully characterized including X-ray diffraction. A combined experimental and theoretical study shows that both the heteroatom and the substitution pattern impact the optical and redox properties.
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| http://dx.doi.org/10.1021/acs.joc.8b02884 | DOI Listing |
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