The c-phosphanylimine L1 was employed for the synthesis of the novel titanaaziridine 1 with an intramolecular phosphine donor side following a reductive complexation route. This coordination mode is new for c-phosphanylimines and compound 1 is the first group 4 complex featuring a c-phosphanylimine ligand.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1039/c8dt04918a | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Antimicrobial Activity and Mode of Action of N-Heterocyclic Carbene Silver(I) Complexes.
Molecules
December 2024
Department of Pharmacy and Interuniversity Research Centre on Bioactive Peptides (CIRPeB), University of Naples "Federico II", Via Montesano 49, 80131 Naples, Italy.
Silver drugs have played a vital role in human healthcare for the treatment of infections for many centuries. Currently, due to antibiotic resistance, a potential scenario or the application of silver complexes may arise as substitutes for conventional antibiotics. In this perspective, N-heterocyclic carbene (NHC) ligands have been selected as carrier molecules for silver ions.
View Article and Find Full Text PDFRisk assessment and quality management in AIO based on CT-linac for nasopharyngeal carcinoma: An improved FMEA and FTA approach.
Med Phys
January 2025
State Key Laboratory of Oncology in South China, Guangdong Key Laboratory of Nasopharyngeal Carcinoma Diagnosis and Therapy, Guangdong Provincial Clinical Research Center for Cancer, Sun Yat-sen University Cancer Center, Guangzhou, P. R. China.
Article Synopsis
- AIO radiotherapy integrates all conventional steps into one device, improving efficiency and reducing errors for cancer patients while facing challenges like software complexity and AI reliance.
- A risk assessment using FMEA and FTA was conducted to evaluate the quality management measures for nasopharyngeal carcinoma treatment.
- Results showed 86 failure modes identified, with risk priority numbers indicating varying levels of risk, emphasizing the importance of implementing quality management measures for safety.
Parallel layered scheme-based integrated orbit-attitude-vibration coupled dynamics and control for large-scale spacecraft.
ISA Trans
December 2024
National Key Laboratory of Aerospace Flight Dynamics, School of Astronautics, Northwestern Polytechnical University, Xi'an 710072, China; Research & Development Institute of Northwestern Polytechnical University in Shenzhen, Shenzhen 518057, China. Electronic address:
This paper investigates an integrated model-control scheme for large-scale spacecraft, focusing on orbit-attitude-vibration dynamics subject to strong time-varying coupling characteristics. The proposed scheme aims to achieve cooperative modeling and control for orbit maintenance, attitude stabilization and vibration suppression simultaneously. An integrated dynamic model is established using the Absolute Nodal Coordinate Formulation and Lagrangian mechanics, where time-varying coupling terms are preserved to enhance model integrity, contrasting with the reduction and decoupling methods commonly adopted in existing literature.
View Article and Find Full Text PDFCrystal structure of di-μ-acetato-κ :-bis{(acetato-κ ,')tetra-aqua-[1-(pyridin-2-yl-methylidene-κ)-2-(pyridin-2-yl-κ)hydrazine-κ ]lanthanum(III)} dinitrate hemihydrate.
Acta Crystallogr E Crystallogr Commun
January 2025
Département de Chimie Faculté des Sciences et Techniques Université Cheik Anta Diop Dakar Senegal.
In the binuclear title complex, [La(CHO)(CHN)(HO)](NO)·0.5HO, the two lanthanum ions are nine coordinate in a distorted trigonal-prismatic geometry. Each La ion is bonded to three N atoms of the Schiff base, 1-(pyridin-2-yl)-2-(pyridin-2-yl-methyl-ene)hydrazine and is coordinated by one acetate group, which acts in -bidentate mode and two acetate groups that act in -mode between the two La ions.
View Article and Find Full Text PDFExploring novel inhibitors for Babesia bigemina lactate dehydrogenase: a computational structural biology perspective.
Parasitol Res
January 2025
Department of Biology, Faculty of Science, Marmara University, Goztepe, 34722, Istanbul, Türkiye.
Babesia bigemina is an apicomplexan parasite responsible for causing "Texas fever" in bovines. Current treatments for bovine babesiosis are hindered by several limitations, including toxicity, insufficient efficacy in eliminating the parasite, and the potential for resistance development. A promising approach to overcome these challenges is the identification of compounds that specifically target essential metabolic pathways unique to the parasite.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!