In a block-assembly task with 138, 4-year-old Chinese kindergarten children, tested in pairs, we manipulated whether fine-grained coordination was required for accomplishing a shared goal with the same end product: building two adjoined towers with alternating levels of orange and green colored blocks to match a depicted model. In the coordination condition, each child had blocks of only one color and built the towers together. In the shared-goal-only condition, each child had both color blocks and built one of the towers, which they then adjoined. We predicted that children in the coordination condition would be more prosocial than children in the shared-goal-only condition. Studies with Western children typically find that girls are more generous than boys. However, we predicted the opposite pattern because Chinese culture emphasizes the importance of generosity more for males than females. Children in the coordination condition were more willing to help their partner complete an unrelated task and were more generous in sharing stickers with unknown children in a dictator game. These results demonstrate that level of coordination affects prosociality above and beyond having a shared goal, and are the first demonstration that prosocial effects of a collaborative task with children generalize beyond the participants to anonymous strangers. Boys shared more stickers with unknown children than girls, suggesting that gender differences in generosity are, in part, culturally conditioned.
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http://dx.doi.org/10.3758/s13423-018-1549-z | DOI Listing |
Anal Methods
January 2025
Department of Chemistry, Birla Institute of Technology and Science Pilani, Hyderabad 500078, India.
In this work, we have explored the metal ion sensing properties of two bisbenzimidazole-based fluorescent probes, that differ in their conformational flexibility, in an aqueous medium. The compound with a flexible methyl spacer (1) experienced blue shifts in its absorption and emission maxima (along with a turn-off response) upon the addition of Hg ions. On the contrary, the compound with a relatively rigid structure (2) showed red shifts in both its absorption and emission maxima (along with a turn-off response) when treated with Hg under similar conditions.
View Article and Find Full Text PDFInorg Chem
January 2025
Henan Key Laboratory of Polyoxometalate Chemistry, College of Chemistry and Molecular Sciences, Henan University, Kaifeng, Henan 475004, P. R. China.
Developing new photocatalysts for the selective oxidation of thioethers to high-value-added sulfoxides under low-oxygen mild conditions is a promising but challenging strategy. Here, a new polyoxometalate-based metal-organic framework (POMOF), , was successfully synthesized, wherein continuous π···π stacking interactions and direct coordination bonds not only strengthen the framework's stability but also accelerate electron transfer. A series of experiments and theoretical studies, including control experiments, kinetic studies, electrochemical spectroscopic analyses, and electron paramagnetic resonance, revealed the synergistic catalytic effect among Co(II) metal centers, BWO, and the photosensitizer TPT.
View Article and Find Full Text PDFNanoscale
January 2025
Laboratoire Softmat, Université de Toulouse, CNRS UMR 5623, 118 route de Narbonne, 31062 Toulouse Cedex 9, France.
Hybrid polyionic complexes (HPICs) are colloidal structures with a charged core rich in metal ions and a neutral hydrophilic corona. Their properties, whether as reservoirs or catalysts, depend on the accessibility and environment of the metal ions. This study demonstrates that modifying the coordination sphere of these ions can tune the properties of HPICs by altering the composition of the complexing block or varying formulation conditions.
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2025
Lab of Applied Biocatalysis, National Engineering Research Center of Wheat and Corn Further Processing, School of Food Science and Engineering, South China University of Technology, No. 381 Wushan Road, Guangzhou 510640, Guangdong China.
Biomineralization of enzymes inside rigid metal-organic frameworks (MOFs) is appealing due to its biocompatibility and simplicity. However, this strategy has hitherto been limited to microporous MOFs, leading to low apparent enzymatic activity. In this study, polysaccharide sodium alginate is introduced during the biomineralization of enzymes in zeolitic imidazolate frameworks (ZIFs) to competitively coordinate with metal ions, which endows the encapsulated enzyme with a 7-fold higher activity than that in microporous ZIFs.
View Article and Find Full Text PDFAppl Ergon
January 2025
Department of Learning Informatics Management and Ethics, Karolinska Institute, Stockholm, Sweden; Paediatric Emergency Department, Karolinska University Hospital, Stockholm, Sweden; Department of Women's and Children's Health, Karolinska Institute, Stockholm, Sweden.
Emergency departments accommodate high-acuity patients in complex, high risk environments with high variability in patient flow and resource availability. Strategies for enabling adaptive capacity are necessary for adjusting activities in response to the variability of overall workload and individual patient acuity. This study aims to identify and describe the strategies used by lead-nurses to inform recommendations for training and education.
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