The goal of the present paper was to elucidate if-and how-the parameters of the Brouers-Sotolongo fractal (BSf) (n,α) kinetic model (α and τ) on the one hand, and of the generalised Brouers-Sotolongo (GBS) isotherm model (a and b) on the other hand, are correlated with adsorption pH and temperature. For that purpose, adsorption of aqueous solutions of two common dyes, methylene blue (MB) and methyl orange (MO) was carried out on four activated carbons (ACs) at three temperatures (25, 35 and 50 °C) and three pH (2.5, 5 and 8). Adsorption kinetics and isotherms were measured, and the corresponding curves were best fitted with specific forms of the aforementioned models, and corresponding to equations known as BSf (1,α) kinetic and Brouers-Gaspard isotherm models. Correlations between all model parameters and adsorption conditions were found, bringing some information about the adsorbate-adsorbent interaction.
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http://dx.doi.org/10.1007/s11356-018-3835-8 | DOI Listing |
ACS Appl Mater Interfaces
January 2025
Key Laboratory of Intelligent Supramolecular Chemistry at the University of Yunnan Province, National and Local Joint Engineering Research Center for Green Preparation Technology of Biobased Materials, School of Chemistry & Environment, Yunnan Minzu University, Kunming 650500, P. R. China.
Developing efficient and recyclable iodine adsorbents is crucial for addressing radioactive iodine pollution. An imidazole cation-bridged pillar[5]arene polymer (P5-P5I) was synthesized via a salt formation reaction. P5-P5I exhibited a high iodine vapor capture capacity of 2130.
View Article and Find Full Text PDFSci Rep
January 2025
Amity Institute of Environmental Sciences (AIES), Amity University Uttar Pradesh (AUUP), Sector-125, Gautam Budh Nagar, Noida, 201313, India.
This study focused on simulating the adsorption-based separation of Methylene Blue (MB) dye utilising Oryza sativa straw biomass (OSSB). Three distinct modelling approaches were employed: artificial neural networks (ANN), adaptive neuro-fuzzy inference systems (ANFIS), and response surface methodology (RSM). To evaluate the adsorbent's potential, assessments were conducted using Fourier-transform infrared spectroscopy (FTIR) and scanning electron microscopy (SEM).
View Article and Find Full Text PDFInt J Biol Macromol
January 2025
Chemical Department, Faculty of Science, Damietta University, Damietta 34517, Egypt.
The study investigated the enhancement of stability and efficacy in the removal of bivalent nickel ions (Ni(II)) by utilizing a cerium metal-organic framework (Ce-MOF) encapsulated within a food-grade algal matrix. This composite material is integrated into a dual-layer hydrogel containing chitosan and carboxymethyl cellulose. The enhancement of structural integrity in the final product can be attributed to the cross-linking process with epichlorohydrin, leading to the development of Ce-MOF-FGA/CMC-CS hydrogel beads.
View Article and Find Full Text PDFScience
January 2025
Wolfson Catalysis Centre, Department of Chemistry, University of Oxford, Oxford, UK.
The distribution of substitutional aluminum (Al) atoms in zeolites affects molecular adsorbate geometry, catalytic activity, and shape and size selectivity. Accurately determining Al positions has been challenging. We used synchrotron resonant soft x-ray diffraction (RSXRD) at multiple energies near the Al K-edge combined with molecular adsorption techniques to precisely locate "single Al" and "Al pairs" in a commercial H-ZSM-5 zeolite.
View Article and Find Full Text PDFEnviron Monit Assess
January 2025
Department of Botany, Bacha Khan University, Charsadda, Charsadda, 24420, Khyber Pakhtunkhwa, Pakistan.
Wastewater is commonly contaminated with many pharmaceutical pollutants, so an efficient purification method is required for their removal from wastewater. In this regard, an innovative tertiary Se/SnO@CMC/Fe-GA nanocomposite was synthesized through encapsulation of metal organic frameworks (Fe-glutaric acid) onto Se/SnO-embedded-sodium carboxy methyl cellulose matrix to thoroughly evaluate its effectiveness for adsorption of levofloxacin drug from wastewater. The prepared Se/SnO@CMC/Fe-GA nanocomposite was analyzed via UV-Vis spectroscopy, Fourier-transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), thermo gravimetric analysis (TGA), energy dispersive X-ray (EDX), and X-ray diffraction (XRD) to valuate optical property, size, morphology, thermal stability, and chemical composition.
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