Magneto-Dielectric Behaviour of M-Type Hexaferrite/Polymer Nanocomposites.

Materials (Basel)

Smart Materials & Nanodielectrics Laboratory, Department of Materials Science, School of Natural Sciences, University of Patras, 26504 Patras, Greece.

Published: December 2018

In the present study two sets of nanocomposites consisting of an epoxy resin and BaFeO or SrFeO nanoparticles were successfully developed and characterized morphologically and structurally via scanning electron microscopy and X-ray diffraction spectra. The dielectric response of the nanocomposites was investigated by means of broadband dielectric spectroscopy and their magnetic properties were derived from magnetization tests. Experimental data imply that the incorporation of the ceramic nanoparticles enhances significantly the dielectric properties of the examined systems and their ability to store electrical energy. Dielectric spectra of all systems revealed the presence of three distinct relaxation mechanisms, which are attributed both to the polymer matrix and the nanoinclusions: Interfacial polarization, glass to rubber transition of the polymer matrix and the re-orientation of small polar side groups of the polymer chain. The magnetic measurements confirmed the ferromagnetic nature of the nanocomposites. The induced magnetic properties increase with the inclusion of hexaferrite nanoparticles. The nanocomposites with SrFeO nanoparticles exhibit higher values of coercive field, magnetization, magnetic saturation and remanence magnetization. A magnetic transition was detected in the ZFC/FC curves in the case of the BaFeO/epoxy nanocomposites.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC6316351PMC
http://dx.doi.org/10.3390/ma11122551DOI Listing

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