Experimental and theoretical threshold photoelectron spectra of methylene.

The threshold photoelectron spectrum of methylene (CH), produced by consecutive H atom abstractions on methane, has been recorded using synchrotron radiation. The experimental spectrum spans the region of the Π ← ionizing transition. It is modeled starting from bending potentials and using the bending approach introduced by Coudert [J. Chem. Phys. , 054302 (2018)] accounting for the quasilinearity of CH and the strong Renner-Teller interaction in . This first calculation yields a theoretical threshold photoelectron spectrum which is in moderate agreement with the experimental one. A more accurate approach treating the three vibrational modes is developed for computing the threshold photoelectron spectrum of triatomic molecules. This new treatment is tested modeling the already measured threshold photoelectron spectrum of the Π ← ionizing transition of the water molecule. The threshold photoelectron spectrum of CH computed with the new approach compares more favorably with the experimental spectrum and yields an adiabatic ionization potential of 10.386(6) eV.