High-density polyethylene (HDPE) and poly(lactic) acid (PLA) blends with different ratios of both polymers, namely, 30:70, 50:50, and 70:30, were produced. Polyethylene-grafted maleic anhydride and a random copolymer of ethylene and glycidyl methacrylate were also considered as compatibilizers to modify HDPE/PLA optimal blends and were added in the amounts of 1, 3, and 5 wt.%. Different properties of the blends were evaluated by performing tensile tests and scanning electron microscopy to analyze blend and interfaces morphology. Moreover, thermomechanical analysis through differential scanning calorimetry, thermo-gravimetric analysis, and infrared spectroscopy were also performed. The blend containing equal amounts of HDPE and PLA seemed to present a good balance between amount of bio-derived charge and acceptable mechanical properties. This suggests that these blends have a good potential for the production of composites with lingo-cellulosic fillers.
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http://dx.doi.org/10.3390/ma11122527 | DOI Listing |
Materials (Basel)
January 2025
Department of Electromechanical Engineering, University of Beira Interior, Rua Marquês de D'Ávila e Bolama, 6201-001 Covilhã, Portugal.
This study investigates the mechanical properties of thermoplastic polyurethane (TPU) 60A, which is a flexible material that can be used to produce soft robotic grippers using additive manufacturing. Tensile tests were conducted under ISO 37 and ISO 527 standards to assess the effects of different printing orientations (0°, 45°, -45°, 90°, and quasi-isotropic) and test speeds (2 mm/min, 20 mm/min, and 200 mm/min) on the material's performance. While the printing orientations at 0° and quasi-isotropic provided similar performance, the quasi-isotropic orientation demonstrated the most balanced mechanical behavior, establishing it as the optimal choice for robust and predictable performance, particularly for computational simulations.
View Article and Find Full Text PDFConf Proc Int Conf Image Form Xray Comput Tomogr
August 2024
Department of Radiology, Perelman School of Medicine, Philadelphia, PA, USA.
Respiratory motion phantoms can be used for evaluation of CT imaging technologies such as motion artifact reduction algorithms and deformable image registration. However, current respiratory motion phantoms do not exhibit detailed lung tissue structures and thus do not provide a realistic testing environment. This paper presents PixelPrint, a method for 3D-printing deformable lung phantoms featuring highly realistic internal structures, suitable for a broad range of CT evaluations, optimizations, and research.
View Article and Find Full Text PDFAdv Mater
January 2025
National Engineering Research Center for Colloidal Materials, School of Chemistry and Chemical Engineering, Shandong University, Jinan, Shandong, 250100, P. R. China.
The hardness of thermoplastic elastomers (TPEs) significantly influences their suitability for various applications, but traditionally, enhancing hardness reduces toughness. Herein a method is introduced that leverages hybrid soft segments to fine-tune the hardness of TPEs without compromising their exceptional toughness. Through the selective copolymerization of polytetramethylene ether glycols (PTMEGs) at various molecular weights, supramolecular poly(urethane-urea) TPEs are molecularly engineered to cover a wide spectrum of hardness while retaining good toughness.
View Article and Find Full Text PDFChem Commun (Camb)
January 2025
Department of Applied Science and Technology, Politecnico di Torino, Viale Teresa Michel 5, 15121 Alessandria, Italy.
In polymer science and technology, the distinction between thermoplastic and thermosetting materials has always been sharp, clear, and well-documented: indeed, the former can theoretically be reprocessed a potentially infinite number of times by heating, forming, and subsequent cooling. This cannot be done in the case of thermosetting polymers due to the presence of cross-links that covalently bind the macromolecular chains, giving rise to insoluble and infusible polymeric networks. In 2011, the discovery of vitrimers revolutionized the classification mentioned above, demonstrating the possibility of using new materials that consist of covalent adaptable networks (CANs): this way, they can change their topology through thermally-activated bond-exchange reactions.
View Article and Find Full Text PDFAnal Chim Acta
February 2025
Department of Pharmaceutical Chemistry, Medical University of Gdansk, Hallera 107, 80-416, Gdansk, Poland.
Background: Benzodiazepine abuse remains a significant public health concern. Current sample preparation methods for benzodiazepine analysis from human serum often involve complex procedures that require large sample volumes and extensive organic solvent use. To address these limitations, this study presents a novel and efficient sample preparation method utilizing 3D-printed sorbent devices.
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