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Correspondence on "Preorganization and Cooperation for Highly Efficient and Reversible Capture of Low-Concentration CO by Ionic Liquids". | LitMetric
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Correspondence on "Preorganization and Cooperation for Highly Efficient and Reversible Capture of Low-Concentration CO by Ionic Liquids".

Marcileia Zanatta Nathalia M Simon Francisco P Dos Santos Marta C Corvo Eurico J Cabrita Jairton Dupont

Angew Chem Int Ed Engl

Institute of Chemistry-, Universidade Federal do Rio Grande do Sul, Av. Bento Gonçalves, 9500, Porto Alegre, 91501-970, RS, Brazil.

Published: January 2019

The preorganization and cooperation mechanism of imide-based ionic liquids reported in a recent Communication was evocated to rationalize the extremely high gravimetric CO capture displayed by these fluids. An analysis of the reported spectroscopic evidences together with additional experiments led to the proposition of an alternative, simpler, and feasible mechanism involving the formation of bicarbonate.

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http://dx.doi.org/10.1002/anie.201712252DOI Listing

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