A 16-electron iridium organometallic is reacted with carbon monoxide to form an 18-electron CO-adduct. This CO-adduct is stable for weeks in the solid state, but quickly reverts to its parent 16-e complex in tetrahydrofuran solution, releasing CO. Using a simple methodology, we show that this gas can subsequently be used to perform a carbonylation reaction on another molecule.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC6275942 | PMC |
| http://dx.doi.org/10.1021/acsomega.8b02154 | DOI Listing |
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