A novel kind of g-C₃N₄/rectorite composite with high visible-light photoactivity was developed via a mild and cost effective two-step process. Ciprofloxacin (CIP), a typical antibiotic, was applied to evaluate the photoactivity of the received catalysts. Furthermore, the by-products of CIP photodegradation were analyzed and the possible degradation pathways were also discussed. Compared with bare photocatalysts, the received composite possessed well reusability and higher photoactivity towards CIP. According to the characterization analysis results, layered g-C₃N₄ was successfully immobilized on layered rectorite, which could not only promote its adsorption capacity but also provide more reactive sites for CIP adsorption and photodegradation. Compared with bare g-C₃N₄, the photoactivity of the prepared composite was significantly enhanced. The enhancement should be mainly due to the lower recombination rate of photogenerated carriers and the improved adsorption capacity toward CIP. This study demonstrated that the obtained g-C₃N₄/rectorite composite should be a promising alternative material in wastewater treatment.
Download full-text PDF |
Source |
|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC6317028 | PMC |
| http://dx.doi.org/10.3390/ma11122452 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Biopolymer Meets Nanoclay: Rational Fabrication of Superb Adsorption Beads from Green Precursors for Efficient Capture of Pb(II) and Dyes.
Nanomaterials (Basel)
April 2024
College of Chemistry and Chemical Engineering, Inner Mongolia University, Hohhot 010021, China.
Renewable, green, and safe natural biopolymer-derived materials are highly desired for the purification of pollutants, but significantly improving their performance without the introduction of additional harmful chemicals remains a huge challenge. Based on the concept of "structure optimization design", environment-friendly composite beads (named SA/PASP/RE) with excellent adsorption performance and recyclability were rationally constructed through a green ionic crosslinking route, using the completely green biopolymer sodium alginate (SA), sodium salt of polyaspartic acid (PASP), and the natural nanoclay rectorite (RE) as starting materials. The nano-layered RE was embedded in the polymer matrix to prevent the polymer chain from becoming over-entangled so that more adsorption sites inside the polymer network were exposed, which effectively improved the mass transfer efficiency of the adsorbent and the removal rate of contaminants.
View Article and Find Full Text PDFCarbon-in-Silicate Nanohybrid Constructed by In Situ Confined Conversion of Organics in Rectorite for Complete Removal of Dye from Water.
Nanomaterials (Basel)
September 2023
College of Chemistry and Chemical Engineering, Inner Mongolia University, Hohhot 010021, China.
The complete removal of low concentration organic pollutants from wastewater to obtain clean water has always been a highly desired but challenging issue. In response to this, we proposed a new strategy to fabricate a carbon-in-silicate nanohybrid composite by recycling dye-loaded layered clay adsorbent and converting them to new heterogeneous carbon-in-silicate nanocomposite through an associated calcination-hydrothermal activation process. It has been confirmed that most of the dye molecules were present in waste rectorite adsorbent using an intercalation mode, which can be in situ converted to carbon in the confined interlayer spacing of rectorite.
View Article and Find Full Text PDFChitosan-based composite hydrogel with a rigid-in-flexible network structure for pH-universal ultra-efficient removal of dye.
Int J Biol Macromol
June 2023
College of Chemistry and Chemical Engineering, Inner Mongolia University, Hohhot 010021, PR China. Electronic address:
Polysaccharide-based hydrogel adsorbents become popular because of their high adsorption capacity and fast adsorption rate, but their low removal rate and poor pH resistance have always been fatal shortcomings. Herein, a feasible strategy was proposed to strengthen the ability of hydrogel adsorbent to remove organic pollutants (i.e.
View Article and Find Full Text PDFEffect of calcination temperatures on the performance of rectorite for cadmium immobilization in soil: Freeze-thaw, plant growth, and microbial diversity.
Environ Res
January 2023
School of Chemistry and Environmental Engineering, Wuhan Institute of Technology, Wuhan, 430205, China; Key Laboratory of Green Chemical Engineering Process of Ministry of Education, Wuhan Institute of Technology, Wuhan, 430205, China; Hubei Engineering Technology Research Center for Chemical Industry Pollution Control, Wuhan, 430205, China; Key Laboratory of Novel Biomass-Based Environmental and Energy Materials in Petroleum and Chemical Industry, Wuhan, 430074, China. Electronic address:
The immobilization of cadmium (Cd(II)) in soil using calcined rectorite (REC) was investigated in this research. The results of immobilization show that a small amount of REC calcined at 700 °C (REC-700 °C) could effectively immobilize 90% of Cd(II) in soil, while the immobilization efficiency of REC only reached 42%. Moreover, the immobilization efficiency of REC calcined at 300 °C and 500 °C (REC-300 °C and REC-500 °C) were lower than REC.
View Article and Find Full Text PDFFabrication of cellulose/rectorite composite films for sustainable packaging.
Int J Biol Macromol
January 2023
Key Laboratory for Advanced Technology in Environmental Protection of Jiangsu Province, School of Materials Science and Engineering, Yancheng Institute of Technology, Yancheng 224051, China. Electronic address:
In order to reduce the environmental pollution caused by plastic packaging, the development of biodegradable high-performance packaging materials has become a research hotspot. Cellulose is a promising food packaging material, but it usually lacks sufficient ultraviolet (UV) shielding property and mechanical strength. In this work, rectorite microplates were incorporated into the cellulose matrix by a facile blending method to fabricate the composite films.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!