Graphitic carbon nitride (g-CN) is a visible light active semiconductor. However, low conductivity and high recombination rate of photogenerated electrons and holes limit its application in photocatalysis. In this work, we design and synthesize hierarchically porous zinc oxide/graphitic carbon nitride (ZnO/g-CN) microspheres with type-II heterojunction to effectively degrade rhodamine B (RhB) via increasing the charge-separation efficiency. The ultraviolet-visible (UV-Vis) absorption spectra, Mott-Schottky plots and valence band X-ray photoelectron spectroscope confirm the formation of type-II heterojunction between ZnO nanocrystals and g-CN nanosheets. As a result, the 1.5-ZnO/g-CN composite (the mass ratio of zinc acetate dihydrate to g-CN is 1.5) exhibits the highest photocatalytic activity with good stability and higher photocatalytic degradation rate comparing to pure g-CN and pure ZnO. In addition, our results confirm that O and h are the main active species for ZnO/g-CN in degradation of RhB.
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