In this Letter, we propose a nonreciprocal heterostructure which combines magnetism and chirality in a simple, easy-to-fabricate design and exhibits at least two orders of magnitude larger magnetochiral dichroism, compared to other proposed metamaterials. This effect stems from the simultaneous lack of time-reversal and space-inversion symmetries and is enhanced by collective slow-photon modes originating from the strong bending of the photonic bands at the Brillouin zone boundaries. We investigate the optical properties of this bianisotropic multilayer heterostructure, consisting of consecutive bilayers of chiral and magnetic materials, embedded in air, and discuss the associated photonic band structure and transmission/absorption spectra obtained by means of full electrodynamic calculations.
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http://dx.doi.org/10.1364/OL.43.005741 | DOI Listing |
Nanoscale
January 2025
Laboratoire National des Champs Magnétiques Intenses (LNCMI), Univ. Grenoble Alpes, INSA Toulouse, Univ. Toulouse Paul Sabatier, EMFL, CNRS, Grenoble, France.
We report herein on the magneto-chiral dichroism (MChD), investigated through near infrared light absorption, of a chiral nanomagnet showing room temperature magneto-electric coupling. The MChD signal associated with the Yb center is driven by the magnetic dipole allowed character of the F ← F electronic transition (|Δ| = 1). Magnetic field and temperature dependence studies reveal an MChD signal that follows the material magnetization and persists at room temperature.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
January 2025
Tianjin Key Lab for Rare Earth Materials and Applications, Renewable Energy Conversion and Storage Center (RECAST), Smart Sensing Interdisciplinary Science Center, School of Materials Science and Engineering, National Institute for Advanced Materials, Nankai University, Tianjin, 300350, China.
The interplay between chirality with magnetism can break both the space and time inversion symmetry and have wide applications in information storage, photodetectors, multiferroics and spintronics. Herein, we report the chiral transition-metal complex cation-based lead halide, R-CDPB and S-CDPB. In contrast with the traditional chiral metal halides with organic cations, a novel strategy for chirality transfer from the transition-metal complex cation to the lead halide framework is developed.
View Article and Find Full Text PDFSci Rep
October 2024
Laboratory for Pohang Emergent Materials and Max Planck POSTECH Center for Complex Phase Materials, Pohang University of Science and Technology, Pohang, 37673, South Korea.
Structural chirality and magnetism, when intertwined, can have profound implications on materials properties. Using X-ray imaging and spectroscopic measurements that leverage the natural and magnetic circular dichroic effects present in magnetized chiral crystal structures, we probe the interplay between chirality and magnetism across the field-induced spin-flop transition of Dy ferroborate, ( ) . Deconvolution of natural and magnetic circular dichroic signals at the Fe K and Dy L absorption edges of the non-centrosymmetric structure was enabled by use of tunable temperature and magnetic field, providing access to element-specific magnetic information across the spin-flop transition.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
December 2024
Laboratoire National des Champs Magnétiques Intenses, CNRS, Univ. Grenoble Alpes, INSA Toulouse, Univ. Toulouse Paul Sabatier, EMFL, F-38042, Grenoble, France.
Here we report on the Magneto-Chiral Dichroism (MChD) detected through visible and near-infrared light absorption of two enantiomeric pairs of Er and Tm chiral complexes featuring a propeller-like molecular structure. The magnetic properties show typical features of isolated paramagnetic ions associated with I and H ground state terms. MChD spectroscopy shows high g dissymmetry factors of ca.
View Article and Find Full Text PDFJ Am Chem Soc
August 2024
Laboratoire National des Champs Magnétiques Intenses (LNCMI), CNRS, Univ. Grenoble Alpes, INSA Toulouse, Univ. Toulouse Paul Sabatier, EMFL, 38042 Grenoble, France.
Magnetic materials are widely used for many technologies in energy, health, transportation, computation, and data storage. For the latter, the readout of the magnetic state of a medium is crucial. Optical readout based on the magneto-optical Faraday effect was commercialized but soon abandoned because of the need for a complex circular polarization-sensitive readout.
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