L-Glutamine-assisted synthesis of ZnO oatmeal-like/silver composites as an electrochemical sensor for Pb detection.

We report a green synthesis of oatmeal ZnO/silver composites in the presence of L-glutamine as an electrochemical sensor for Pb detection. The synthesis was performed via the direct reduction of Ag in the presence of L-glutamine in NaOH. X-ray diffraction indicated that the Ag was completely reduced to metallic Ag. The field emission scanning electron microscopy (FESEM) and energy dispersive X-ray results confirmed an oatmeal-like morphology of the ZnO with the presence of Ag. The FESEM images showed the effect of L-glutamine on the ZnO morphology. The EIS results confirmed a significant decrease in the charge transfer resistance of the modified glassy carbon electrode due to the presence of Ag. From the differential pulse voltammetry results, a linear working range for the concentration of Pb between 5 and 6 nM with LOD of 0.078 nM (S/N = 3) was obtained. The sensitivity of the linear segment is 1.42 μA nM cm. The presence of L-glutamine as the capping agent and stabilizer decreases the size of Ag nanoparticles and prevents the agglomeration of ZnO, respectively. Graphical abstract ᅟ.