The unbalanced MOF-on-MOF growth of MIL-88A on the MIL-88B template, where both MOFs have a similar three-dimensional hexagonal structure but with mismatched cell parameters, results in the formation of an atypical lopsided core-shell of MIL-88B@MIL-88A with an off-centered core. The formation mechanism of the lopsided core-shell of MIL-88B@MIL-88A is verified via monitoring the growth process.
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Unbalanced MOF-on-MOF growth for the production of a lopsided core-shell of MIL-88B@MIL-88A with mismatched cell parameters.
Chem Commun (Camb)
December 2018
Department of Chemistry, Yonsei University, 50 Yonsei-ro, Seodaemun-gu, Seoul 120-749, Korea.
The unbalanced MOF-on-MOF growth of MIL-88A on the MIL-88B template, where both MOFs have a similar three-dimensional hexagonal structure but with mismatched cell parameters, results in the formation of an atypical lopsided core-shell of MIL-88B@MIL-88A with an off-centered core. The formation mechanism of the lopsided core-shell of MIL-88B@MIL-88A is verified via monitoring the growth process.
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