This paper addresses the localization of a gas emission source within a real-world human environment with a mobile robot. Our approach is based on an efficient and coherent system that fuses different sensor modalities (i.e., vision and chemical sensing) to exploit, for the first time, the semantic relationships among the detected gases and the objects visually recognized in the environment. This novel approach allows the robot to focus the search on a finite set of potential gas source candidates (dynamically updated as the robot operates), while accounting for the non-negligible uncertainties in the object recognition and gas classification tasks involved in the process. This approach is particularly interesting for structured indoor environments containing multiple obstacles and objects, enabling the inference of the relations between objects and between objects and gases. A probabilistic Bayesian framework is proposed to handle all these uncertainties and semantic relations, providing an ordered list of candidates to be the source. This candidate list is updated dynamically upon new sensor measurements to account for objects not previously considered in the search process. The exploitation of such probabilities together with information such as the locations of the objects, or the time needed to validate whether a given candidate is truly releasing gases, is delegated to a path planning algorithm based on Markov decision processes to minimize the search time. The system was tested in an office-like scenario, both with simulated and real experiments, to enable the comparison of different path planning strategies and to validate its efficiency under real-world conditions.
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http://dx.doi.org/10.3390/s18124174 | DOI Listing |
Acc Chem Res
January 2025
The Wolfson Catalysis Centre, Department of Chemistry, University of Oxford, Oxford OX1 3QR, U.K.
ConspectusThe discovery of reversible hydrogenation using metal-free phosphoborate species in 2006 marked the official advent of frustrated Lewis pair (FLP) chemistry. This breakthrough revolutionized homogeneous catalysis approaches and paved the way for innovative catalytic strategies. The unique reactivity of FLPs is attributed to the Lewis base (LB) and Lewis acid (LA) sites either in spatial separation or in equilibrium, which actively react with molecules.
View Article and Find Full Text PDFBio Protoc
January 2025
University of Bordeaux, CNRS, IBGC UMR 5095, Bordeaux, France.
Stable-isotope resolved metabolomics (SIRM) is a powerful approach for characterizing metabolic states in cells and organisms. By incorporating isotopes, such as C, into substrates, researchers can trace reaction rates across specific metabolic pathways. Integrating metabolomics data with gene expression profiles further enriches the analysis, as we demonstrated in our prior study on glioblastoma metabolic symbiosis.
View Article and Find Full Text PDFAdv Mater
January 2025
Key Laboratory of Organic Optoelectronics and Molecular Engineering of the Ministry of Education, Department of Chemistry, Tsinghua University, Beijing, 100084, P. R. China.
Advanced carbon materials are widely utilized in wearable electronics. Nevertheless, the production of carbon materials from fossil-based sources raised concerns regarding their non-renewability, high energy consumption, and the consequent greenhouse gas emissions. Biopolymers, readily available in nature, offer a promising and eco-friendly alternative as a carbon source, enabling the sustainable production of carbon materials for wearable electronics.
View Article and Find Full Text PDFLangmuir
January 2025
Laboratory of Advanced Light Alloy Materials and Devices, Yantai Nanshan University, Longkou 265713, China.
Hydrogen gas holds immense promise as a clean fuel source, yet its widespread adoption faces significant challenges in storage and transportation due to its gaseous and highly flammable nature. An increasingly attractive approach to overcoming these limitations involves reacting aluminum (Al) blocks with water to produce hydrogen, providing an alternative distribution mechanism in which Al blocks can be used as "hydrogen storage" for on-demand production at any location. However, current methods suffer poor hydrogen production rates and yields, primarily influenced by the limited contact area between Al and the catalyst, such as Ga-based room-temperature liquid metal.
View Article and Find Full Text PDFInorg Chem
January 2025
Frontiers Science Center for New Organic Matter, Key Laboratory of Advanced Energy Materials Chemistry (MOE), College of Chemistry, Nankai University, Tianjin 300071, China.
The fixation of carbon dioxide (CO) directly from flue gas into valuable chemicals like 2-oxazolidinones is of great significance for economic and environmental benefits, which is typically catalyzed by noble-metal catalysts and under harsh conditions. Herein, a novel 2-fold interpenetrated framework {[Co(μ-O)(TCA)(HDPTA)]·2HO·2DMF} [Co(II)-based metal-organic framework ()] containing [Co] clusters and highly dense amino groups (-NH) dispersed in the channel was prepared, exhibiting high solvent/pH stability and CO adsorption capacity (24.9 cm·g).
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