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Diastereoselective solid-state crossed photocycloaddition of olefins in a 3D Zn(ii) coordination polymer. | LitMetric

AI Article Synopsis

  • 1,2-Bis(4-pyridyl)ethylene reacts with allyl groups from allylmalonate when exposed to light, initiating a [2+2] cross-cycloaddition reaction.
  • This reaction occurs within the pores of a specific 3D metal-organic framework (MOF) designated as [Zn2(H2O)2(Amal)2(bpe)].
  • The outcome is the formation of a new 3D MOF with a different spatial arrangement or topology.

Article Abstract

1,2-Bis(4-pyridyl)ethylene undergoes a photoinitiated [2+2] cross-cycloaddition reaction with allyl groups of allylmalonate in pores of a 3D metal-organic framework (MOF) [Zn2(H2O)2(Amal)2(bpe)] to produce a 3D MOF with a new topology.

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Source
http://dx.doi.org/10.1039/c8cc07734gDOI Listing

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