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Function-Integrated Ru Catalyst for Photochemical CO Reduction. | LitMetric
Visible-light-driven catalytic reduction of CO is at the heart of artificial photosynthesis. Here, we demonstrate the first example of a Ru complex that can function both as a photosensitizer and catalyst for CO reduction. The catalyst exhibited excellent activity for CO evolution with a high turnover number (TON, 353 for 24 h), reaction rate (TOF, 14.7 h), and product selectivity (97%) under visible-light irradiation. We also succeeded in selective product formation (CO or HCOOH) by changing the basicity of the reaction media. This finding will open new avenues for visible-light-driven photoredox catalysis using Ru-based function-integrated photocatalysts.
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