We report a multi-pass tunable diode laser absorption spectrometer based on the frequency-modulation spectroscopy (FMS) technique. It has the advantage of high scan speed and is immune to the etalon effect. A multi-pass Herriott-type cell was used in the spectrometer to increase the effective optical length to 17.5 m and compact the physical dimensions of the spectrometer to 60×30×30 cm. Noise due to low-frequency fluctuation of the laser power and the 1/f noise in the rapid detection are sufficiently reduced by FMS. Interference fringes are effectively suppressed when the modulation frequency equals to integer or half-integer times of their free spectral range (FSR). An absorption line of CH around 1.51 µm was recorded with the spectrometer to demonstrate its capabilities. The response frequency of the spectrometer is up to 100 kHz (10 µs) thanks to the high modulation frequency of FMS. The detection sensitivity of the spectrometer is about 240 ppb (3σ) at 100 kHz measurement repetition rate. The amplitude of the absorption signal is highly linear to the CH concentration in the range of 300 ppb -100 ppm. Based on the Allan variation, the detection limit was determined to be 18 ppb with a detection time of 166 s.
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http://dx.doi.org/10.1364/OE.26.029330 | DOI Listing |
Spectrochim Acta A Mol Biomol Spectrosc
March 2025
College of Physics and Electronic Engineering, Jiangsu Normal University, Xuzhou 221116, PR China. Electronic address:
Accurate determination of spectral parameters for carbon monoxide (CO) transitions is crucial for the development of laser absorption spectroscopy-based CO sensors. This study reports the measurement of line strengths, self-broadening coefficients, and their temperature-dependent exponents for three transitions in the first overtone band near 2.3 μm.
View Article and Find Full Text PDFNat Commun
January 2024
Department of Materials Science and Engineering, Korea Advanced Institute of Science and Technology (KAIST), Daejeon, 34141, Republic of Korea.
Switchable tribological properties of ferroelectrics offer an alternative route to visualize and control ferroelectric domains. Here, we observe the switchable friction and wear behavior of ferroelectrics using a nanoscale scanning probe-down domains have lower friction coefficients and show slower wear rates than up domains and can be used as smart masks. This asymmetry is enabled by flexoelectrically coupled polarization in the up and down domains under a sufficiently high contact force.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
March 2024
Key Laboratory of Optical Information Detection and Display Technology of Zhejiang, Zhejiang Normal University, Jinhua 321004, China. Electronic address:
The simultaneous detection of fractional exhaled nitric oxide (FeNO) and end-tidal carbon dioxide (ETCO) is of great importance for the distinguishing and diagnosis of asthma and chronic obstructive pulmonary disease (COPD), providing more comprehensive information on respiratory disorders. This work demonstrates a simultaneous ETCO and FeNO detection system based on quantum cascade laser absorption spectroscopy (QCLAS) technology was presented. The system employs wavelength modulation spectroscopy (WMS) technology and the Herriott multi-pass cell, achieving a detection limit of 2.
View Article and Find Full Text PDFRev Sci Instrum
November 2023
Hefei National Research Center for Physical Sciences at the Microscale and Department of Chemical Physics, University of Science and Technology of China, Hefei, Anhui 230026, People's Republic of China.
We present an ultra-sensitive continuous wave cavity ringdown spectroscopy (cw-CRDS) spectrometer to record high resolution spectra of reactive radicals and ions in a pulsed supersonic plasma. The spectrometer employs a home-made external cavity diode laser as the tunable light source, with its wavelength modulated by radio-frequency white noise. The ringdown cavity with a finesse of ∼105 is arranged with an off-axis alignment.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
December 2023
College of Control Science & Engineering, China University of Petroleum (East China), Qingdao 266580, PR China.
In the process of oil and gas exploration and development, carbon isotope ratio can reflect the maturity of oil and gas and predict the recovery factor, and the isotope ratio in the composition of shale gas is particularly important. Thus, a carbon isotope spectrum logging system was designed and exploited based on tunable diode laser absorption spectroscopy (TDLAS) technology under the fundamental frequency absorption band of CO and CO molecules, and a quantum cascade laser (QCL) with center wavelength of 4.35 μm was applied.
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