By using the strong nonlinear effect and ultrafast electronic response of cholesteric liquid crystals (CLC), ultrafast all optical switching between polarization vortex and phase vortex is realized in a system combining CLC and q-plate. The experimental result shows that switching with high modulation depth can be accomplished in less than 1 picosecond. Furthermore, CLC and q-plates will enable compact integrated devices with sub-mm thicknesses.
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http://dx.doi.org/10.1364/OE.26.028818 | DOI Listing |
Chem Sci
January 2025
Department of Chemistry, The University of Adelaide Adelaide South Australia 5005 Australia
Singlet fission (SF) is a process that is potentially beneficial for photovoltaics by producing two triplet excitons from a single photon, but its application is often hindered by the inability to effectively separate the resultant triplet excitons. It has been proposed that an energy gradient can assist in separating triplet excitons through triplet energy transfer between chromophores of different triplet energies, but this approach has only been studied in solution and the efficacy of this strategy in the solid state is under explored. Here, we investigate energy-gradient-driven SF in a disordered solid state, in the form of suspensions of 5,12-bis(triisopropylsilylethnyl)tetracene:6,13-bis(triisopropylsilylethnyl)pentance (TIPS-Tn:TIPS-Pn) blend nanoparticles (NPs).
View Article and Find Full Text PDFAdv Mater
January 2025
Henry Royce Institute and Photon Science Institute, Department of Electrical and Electronic Engineering, The University of Manchester, Oxford Road, Manchester, M13 9PL, UK.
As human-machine interface hardware advances, better sensors are required to detect signals from different stimuli. Among numerous technologies, humidity sensors are critical for applications across different sectors, including environmental monitoring, food production, agriculture, and healthcare. Current humidity sensors rely on materials that absorb moisture, which can take some time to equilibrate with the surrounding environment, thus slowing their temporal response and limiting their applications.
View Article and Find Full Text PDFJ Phys Chem C Nanomater Interfaces
January 2025
Department of Mechanical Engineering and Technology Management, Norwegian University of Life Sciences, N-1433 AS, Norway.
Hybrid molecular ferroelectrics with orientationally disordered mesophases offer significant promise as lead-free alternatives to traditional inorganic ferroelectrics owing to properties such as room temperature ferroelectricity, low-energy synthesis, malleability, and potential for multiaxial polarization. The ferroelectric molecular salt HdabcoClO is of particular interest due to its ultrafast ferroelectric room-temperature switching. However, so far, there is limited understanding of the nature of dynamical disorder arising in these compounds.
View Article and Find Full Text PDFAdv Mater
January 2025
Institute of Materials Physics, University of Münster, Wilhelm-Klemm-Str. 10, 48149, Münster, Germany.
As a phase change material (PCM), antimony exhibits a set of desirable properties that make it an interesting candidate for photonic memory applications. These include a large optical contrast between crystalline and amorphous solid states over a wide wavelength range. Switching between the states is possible on nanosecond timescales by applying short heating pulses.
View Article and Find Full Text PDFLight Sci Appl
January 2025
Department of Physics, University of Ottawa, Ottawa, ON, K1N 6N5, Canada.
Graphene has unique properties paving the way for groundbreaking future applications. Its large optical nonlinearity and ease of integration in devices notably makes it an ideal candidate to become a key component for all-optical switching and frequency conversion applications. In the terahertz (THz) region, various approaches have been independently demonstrated to optimize the nonlinear effects in graphene, addressing a critical limitation arising from the atomically thin interaction length.
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