The lifetimes of the first excited 2^{+}, 4^{+}, and 6^{+} states in ^{98}Zr were measured with the recoil-distance Doppler shift method in an experiment performed at GANIL. Excited states in ^{98}Zr were populated using the fission reaction between a 6.2 MeV/u ^{238}U beam and a ^{9}Be target. The γ rays were detected with the EXOGAM array in correlation with the fission fragments identified by mass and atomic number in the VAMOS++ spectrometer. Our result shows a very small B(E2;2_{1}^{+}→0_{1}^{+}) value in ^{98}Zr, thereby confirming the very sudden onset of collectivity at N=60. The experimental results are compared to large-scale Monte Carlo shell model and beyond-mean-field calculations. The present results indicate the coexistence of two additional deformed shapes in this nucleus along with the spherical ground state.
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http://dx.doi.org/10.1103/PhysRevLett.121.192501 | DOI Listing |
Inorg Chem
January 2025
State Key Laboratory of Clean and Efficient Coal Utilization, Taiyuan University of Technology, Taiyuan 030024, China.
The low sulfur selectivity of Fe-based HS-selective catalytic oxidation catalysts is still a problem, especially at a high O content. This is alleviated here through anchoring FeO nanoclusters on UiO-66 via the formation of Fe-O-Zr bonds. The introduced FeO species exist in the form of Fe and Fe.
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2025
State Key Laboratory of Precision Electronic Manufacturing Technology and Equipment, Guangdong Provincial Research Center on Smart Materials and Energy Conversion Devices, Guangdong Provincial Key Laboratory of Functional Soft Condensed Matter, School of Materials and Energy, School of Electromechanical Engineering and School of Integrated Circuits, Guangdong University of Technology, Guangzhou 510006, China.
Lead-based antiferroelectric (AFE) ceramics have the advantages of high power density, fast charge and discharge speed, and the electric-field-induced AFE-FE phase transition, making them one of the potential dielectric energy storage materials. However, the energy storage density still needs to be improved. In this work, (PbCa) (ZrSn)O (PCZS, = 0.
View Article and Find Full Text PDFNat Commun
January 2025
State Key Laboratory of Silicon and Advanced Semiconductor Materials, School of Materials Science and Engineering, Zhejiang University, Hangzhou, 310027, China.
The composition in ferroelectric oxide films is decisive for optimizing properties and device performances. Controlling a composition distribution in these films by a facile approach is thus highly desired. In this work, we report a solution epitaxy of PbZrTiO films with a continuous gradient of Zr concentration, realized by a competitive growth at ~220 °C.
View Article and Find Full Text PDFChem Commun (Camb)
December 2024
School of Energy and Power, Jiangsu University of Science and Technology, Zhenjiang 212003, China.
In this study, solid composite electrolytes (SCEs) comprising UIO-66-F(Zr) were obtained by using a simple solution casting method. By introducing fluorinated groups, the interaction between the MOF and the polymer was significantly improved, which not only stabilizes the SEI layer but also improves the ionic conductivity of the SCEs, thus advancing the practical application of solid composite electrolytes in lithium metal batteries.
View Article and Find Full Text PDFJ Hazard Mater
January 2025
State Key Laboratory for Pollution Control, School of Environmental Science and Engineering, Shanghai Institute of Pollution Control and Ecological Security, Tongji University, 1239 Siping Road, Shanghai 200092, China; China Shipping Environment Technology (Shanghai) Co., Ltd, Shanghai Ship and Shipping Research Institute, 600 Minsheng Road, Shanghai 200135, China. Electronic address:
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